[Code of Federal Regulations]
[Title 40, Volume 11]
[Revised as of July 1, 2003]
From the U.S. Government Printing Office via GPO Access
[CITE: 40CFR63.1205]
[Page 17-19]
TITLE 40--PROTECTION OF ENVIRONMENT
CHAPTER I--ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)
PART 63--NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES--Table of Contents
Subpart EEE--National Emission Standards for Hazardous Air Pollutants
from Hazardous Waste Combustors
Sec. 63.1205 What are the standards for hazardous waste burning lightweight aggregate kilns?
(a) Emission limits for existing sources. You must not discharge or
cause combustion gases to be emitted into the atmosphere that contain:
(1) For dioxins and furans:
(i) Emissions in excess of 0.20 ng TEQ/dscm corrected to 7 percent
oxygen; or
(ii) Rapid quench of the combustion gas temperature at the exit of
the (last) combustion chamber (or exit of any waste heat recovery
system) to 400 F or lower based on the average of the test run average
temperatures. You must also notify in writing the RCRA authority that
you are complying with this option;
(2) Mercury in excess of 120 [mu]g/dscm corrected to 7 percent
oxygen;
(3) Lead and cadmium in excess of 250 [mgr]g/dscm, combined
emissions, corrected to 7 percent oxygen;
(4) Arsenic, beryllium, and chromium in excess of 110 [mgr]g/dscm,
combined emissions, corrected to 7 percent oxygen;
(5) Carbon monoxide and hydrocarbons. (i) Carbon monoxide in excess
of 100 parts per million by volume, over an hourly rolling average
(monitored continuously with a continuous emissions monitoring system),
dry basis and corrected to 7 percent oxygen. If you elect to comply with
this carbon monoxide
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standard rather than the hydrocarbon standard under paragraph (a)(5)(ii)
of this section, you also must document that, during the destruction and
removal efficiency (DRE) test runs or their equivalent as provided by Sec.
63.1206(b)(7), hydrocarbons do not exceed 20 parts per million by volume
during those runs, over an hourly rolling average (monitored
continuously with a continuous emissions monitoring system), dry basis,
corrected to 7 percent oxygen, and reported as propane; or
(ii) Hydrocarbons in excess of 20 parts per million by volume, over
an hourly rolling average, dry basis, corrected to 7 percent oxygen, and
reported as propane;
(6) Hydrochloric acid and chlorine gas in excess of 600 parts per
million by volume, combined emissions, expressed as hydrochloric acid
equivalents, dry basis and corrected to 7 percent oxygen; and
(7) Particulate matter in excess of 57 mg/dscm corrected to 7
percent oxygen.
(b) Emission limits for new sources. You must not discharge or cause
combustion gases to be emitted into the atmosphere that contain:
(1) For dioxins and furans:
(i) Emissions in excess of 0.20 ng TEQ/dscm corrected to 7 percent
oxygen; or
(ii) Rapid quench of the combustion gas temperature at the exit of
the (last) combustion chamber (or exit of any waste heat recovery
system) to 400 F or lower based on the average of the test run average
temperatures. You must also notify in writing the RCRA authority that
you are complying with this option;
(2) Mercury in excess of 120 [mgr]g/dscm corrected to 7 percent
oxygen;
(3) Lead and cadmium in excess of 43 [mgr]g/dscm, combined
emissions, corrected to 7 percent oxygen;
(4) Arsenic, beryllium, and chromium in excess of 110 [mgr]g/dscm,
combined emissions, corrected to 7 percent oxygen;
(5) Carbon monoxide and hydrocarbons. (i) Carbon monoxide in excess
of 100 parts per million by volume, over an hourly rolling average
(monitored continuously with a continuous emissions monitoring system),
dry basis and corrected to 7 percent oxygen. If you elect to comply with
this carbon monoxide standard rather than the hydrocarbon standard under
paragraph (b)(5)(ii) of this section, you also must document that,
during the destruction and removal efficiency (DRE) test runs or their
equivalent as provided by Sec. 63.1206(b)(7), hydrocarbons do not exceed 20
parts per million by volume during those runs, over an hourly rolling
average (monitored continuously with a continuous emissions monitoring
system), dry basis, corrected to 7 percent oxygen, and reported as
propane; or
(ii) Hydrocarbons in excess of 20 parts per million by volume, over
an hourly rolling average, dry basis, corrected to 7 percent oxygen, and
reported as propane;
(6) Hydrochloric acid and chlorine gas in excess of 600 parts per
million by volume, combined emissions, expressed as hydrochloric acid
equivalents, dry basis and corrected to 7 percent oxygen; and
(7) Particulate matter in excess of 57 mg/dscm corrected to 7
percent oxygen.
(c) Destruction and removal efficiency (DRE) standard. (1) 99.99%
DRE. Except as provided in paragraph (c)(2) of this section, you must
achieve a destruction and removal efficiency (DRE) of 99.99% for each
principal organic hazardous constituent (POHC) designated under
paragraph (c)(3) of this section. You must calculate DRE for each POHC
from the following equation:
DRE = [1--(Wout / Win)] x 100%
Where:
Win = mass feedrate of one principal organic hazardous
constituent (POHC) in a waste feedstream; and
Wout = mass emission rate of the same POHC present in exhaust
emissions prior to release to the atmosphere.
(2) 99.9999% DRE. If you burn the dioxin-listed hazardous wastes
F020, F021, F022, F023, F026, or F027 (see Sec. 261.31 of this chapter),
you must achieve a destruction and removal efficiency (DRE) of 99.9999%
for each principal organic hazardous constituent (POHC) that you
designate under paragraph (c)(3) of this section. You must demonstrate
this DRE performance on POHCs that are more difficult to incinerate than
tetra-, penta-, and hexachloro dibenzo-dioxins and
[[Page 19]]
dibenzofurans. You must use the equation in paragraph (c)(1) of this
section to calculate DRE for each POHC. In addition, you must notify the
Administrator of your intent to burn hazardous wastes F020, F021, F022,
F023, F026, or F027.
(3) Principal organic hazardous constituents (POHCs). (i) You must
treat the Principal Organic Hazardous Constituents (POHCs) in the waste
feed that you specify under paragraph (c)(3)(ii) of this section to the
extent required by paragraphs (c)(1) and (c)(2) of this section.
(ii) You must specify one or more POHCs from the list of hazardous
air pollutants established by 42 U.S.C. 7412(b)(1), excluding
caprolactam (CAS number 105602) as provided by Sec. 63.60, for each waste
to be burned. You must base this specification on the degree of
difficulty of incineration of the organic constituents in the waste and
on their concentration or mass in the waste feed, considering the
results of waste analyses or other data and information.
(d) Significant figures. The emission limits provided by paragraphs
(a) and (b) of this section are presented with two significant figures.
Although you must perform intermediate calculations using at least three
significant figures, you may round the resultant emission levels to two
significant figures to document compliance.
[67 FR 6812, Feb. 13, 2002, as amended at 67 FR 77691, Dec. 19, 2002]
Monitoring and Compliance Provisions