[Code of Federal Regulations] [Title 40, Volume 11] [Revised as of July 1, 2003] From the U.S. Government Printing Office via GPO Access [CITE: 40CFR63.1206] [Page 19-33] TITLE 40--PROTECTION OF ENVIRONMENT CHAPTER I--ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) PART 63--NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES--Table of Contents Subpart EEE--National Emission Standards for Hazardous Air Pollutants from Hazardous Waste Combustors Sec. 63.1206 When and how must you comply with the standards and operating requirements? (a) Compliance dates--(1) Compliance date for existing sources. You must comply with the standards of this subpart no later than the compliance date, September 30, 2003, unless the Administrator grants you an extension of time under Sec. 63.6(i) or Sec. 63.1213. (2) New or reconstructed sources. (i) If you commenced construction or reconstruction of your hazardous waste combustor after April 19, 1996, you must comply with this subpart by the later of September 30, 1999 or the date the source starts operations, except as provided by paragraph (a)(2)(ii) of this section. The costs of retrofitting and replacement of equipment that is installed specifically to comply with this subpart, between April 19, 1996 and a source's compliance date, are not considered to be reconstruction costs. (ii) For a standard in this subpart that is more stringent than the standard proposed on April 19, 1996, you may achieve compliance no later than September 30, 2003 if you comply with the standard proposed on April 19, 1996 after September 30, 1999. This exception does not apply, however, to new or reconstructed area source hazardous waste combustors that become major sources after September 30, 1999. As provided by Sec. 63.6(b)(7), such sources must comply with this subpart at startup. (3) Early compliance. If you choose to comply with the emission standards of this subpart prior to September 30, 2003, your compliance date is the date you postmark the Notification of Compliance under Sec. 63.1207(j)(1). (b) Compliance with standards--(1) Applicability. The emission standards and operating requirements set forth in this subpart apply at all times except: (i) During periods of startup, shutdown, and malfunction; and (ii) When hazardous waste is not in the combustion chamber (i.e., the hazardous waste feed to the combustor has been cut off for a period of time not less than the hazardous waste residence time) and you have documented in the operating record that you are complying with all otherwise applicable requirements and standards promulgated under authority of sections 112 (e.g., subpart LLL of this part for cement kilns) or 129 of the Clean Air Act in lieu of the emission standards of Secs. 63.1203 through 63.1205; the monitoring and compliance standards of this section and Secs. 63.1207 through 63.1209, except the modes of operation requirements of Sec. 63.1209(q); and the notification, reporting, and recordkeeping requirements of Secs. 63.1210 through 63.1212. (2) Methods for determining compliance. The Administrator will determine compliance with the emission standards of this subpart as provided by Sec. 63.6(f)(2). [[Page 20]] Conducting performance testing under operating conditions representative of the extreme range of normal conditions is consistent with the requirements of Secs. 63.6(f)(2)(iii)(B) and 63.7(e)(1) to conduct performance testing under representative operating conditions. (3) Finding of compliance. The Administrator will make a finding concerning compliance with the emission standards and other requirements of this subpart as provided by Sec. 63.6(f)(3). (4) Extension of compliance with emission standards. The Administrator may grant an extension of compliance with the emission standards of this subpart as provided by Secs. 63.6(i) and 63.1213. (5) Changes in design, operation, or maintenance--(i) Changes that may adversely affect compliance. If you plan to change (as defined in paragraph (b)(5)(iii) of this section) the design, operation, or maintenance practices of the source in a manner that may adversely affect compliance with any emission standard that is not monitored with a CEMS: (A) Notification. You must notify the Administrator at least 60 days prior to the change, unless you document circumstances that dictate that such prior notice is not reasonably feasible. The notification must include: (1) A description of the changes and which emission standards may be affected; and (2) A comprehensive performance test schedule and test plan under the requirements of Sec. 63.1207(f) that will document compliance with the affected emission standard(s); (B) Performance test. You must conduct a comprehensive performance test under the requirements of Secs. 63.1207(f)(1) and (g)(1) to document compliance with the affected emission standard(s) and establish operating parameter limits as required under Sec. 63.1209, and submit to the Administrator a Notification of Compliance under Secs. 63.1207(j) and 63.1210(d); and (C) Restriction on waste burning. (1) Except as provided by paragraph (b)(5)(i)(C)(2) of this section, after the change and prior to submitting the notification of compliance, you must not burn hazardous waste for more than a total of 720 hours (renewable at the discretion of the Administrator) and only for the purposes of pretesting or comprehensive performance testing. Pretesting is defined at Sec. 63.1207(h)(2)(i) and (ii). (2) You may petition the Administrator to obtain written approval to burn hazardous waste in the interim prior to submitting a Notification of Compliance for purposes other than testing or pretesting. You must specify operating requirements, including limits on operating parameters, that you determine will ensure compliance with the emission standards of this subpart based on available information. The Administrator will review, modify as necessary, and approve if warranted the interim operating requirements. (ii) Changes that will not affect compliance. If you determine that a change will not adversely affect compliance with the emission standards or operating requirements, you must document the change in the operating record upon making such change. You must revise as necessary the performance test plan, Documentation of Compliance, Notification of Compliance, and start-up, shutdown, and malfunction plan to reflect these changes. (iii) Definition of ``change.'' For purposes of paragraph (b)(5) of this section, ``change'' means any change in design, operation, or maintenance practices that were documented in the comprehensive performance test plan, Notification of Compliance, or startup, shutdown, and malfunction plan. (6) Compliance with the carbon monoxide and hydrocarbon emission standards. This paragraph applies to sources that elect to comply with the carbon monoxide and hydrocarbon emissions standards under Secs. 63.1203 through 63.1205 by documenting continuous compliance with the carbon monoxide standard using a continuous emissions monitoring system and documenting compliance with the hydrocarbon standard during the destruction and removal efficiency (DRE) performance test or its equivalent. (i) If a DRE test performed pursuant to Sec. 63.1207(c)(2) is acceptable as documentation of compliance with the DRE standard, you may use the highest hourly rolling average hydrocarbon level achieved during the DRE test runs to document compliance with the [[Page 21]] hydrocarbon standard. An acceptable DRE test is any test for which the data and results are determined to meet quality assurance objectives (on a site-specific basis) such that the results adequately demonstrate compliance with the DRE standard. (ii) If during this acceptable DRE test you did not obtain hydrocarbon emissions data sufficient to document compliance with the hydrocarbon standard, you must either: (A) Perform, as part of the performance test, an ``equivalent DRE test'' to document compliance with the hydrocarbon standard. An equivalent DRE test is comprised of a minimum of three runs each with a minimum duration of one hour during which you operate the combustor as close as reasonably possible to the operating parameter limits that you established based on the initial DRE test. You must use the highest hourly rolling average hydrocarbon emission level achieved during the equivalent DRE test to document compliance with the hydrocarbon standard; or (B) Perform a DRE test as part of the performance test. (7) Compliance with the DRE standard. (i) Except as provided in paragraphs (b)(7)(ii) and (b)(7)(iii) of this section: (A) You must document compliance with the Destruction and Removal Efficiency (DRE) standard under Secs. 63.1203 through 63.1205 only once provided that you do not modify the source after the DRE test in a manner that could affect the ability of the source to achieve the DRE standard. (B) You may use any DRE test data that documents that your source achieves the required level of DRE provided: (1) You have not modified the design or operation of your source in a manner that could effect the ability of your source to achieve the DRE standard since the DRE test was performed; and, (2) The DRE test data meet quality assurance objectives determined on a site-specific basis. (ii) Sources that feed hazardous waste at a location in the combustion system other than the normal flame zone must demonstrate compliance with the DRE standard during each comprehensive performance test; (iii) For sources that do not use DRE previous testing to document conformance with the DRE standard pursuant to Sec. 63.1207(c)(2), you must perform DRE testing during the initial comprehensive performance test. (8) Applicability of particulate matter and opacity standards during particulate matter CEMS correlation tests. (i) Any particulate matter and opacity standards of parts 60, 61, 63, 264, 265, and 266 of this chapter (i.e., any title 40 particulate or opacity standards) applicable to a hazardous waste combustor do not apply while you conduct particulate matter continuous emissions monitoring system (CEMS) correlation tests (i.e., correlation with manual stack methods) under the conditions of paragraphs (b)(8)(iii) through (vii) of this section. (ii) Any permit or other emissions or operating parameter limits or conditions, including any limitation on workplace practices, that are applicable to hazardous waste combustors to ensure compliance with any particulate matter and opacity standards of parts 60, 61, 63, 264, 265, and 266 of this chapter (i.e., any title 40 particulate or opacity standards) do not apply while you conduct particulate matter CEMS correlation tests under the conditions of paragraphs (b)(8)(iii) through (vii) of this section. (iii) For the provisions of this section to apply, you must: (A) Develop a particulate matter CEMS correlation test plan that includes the following information. This test plan may be included as part of the comprehensive performance test plan required under Secs. 63.1207(e) and (f): (1) Number of test conditions and number of runs for each test condition; (2) Target particulate matter emission level for each test condition; (3) How you plan to modify operations to attain the desired particulate matter emission levels; and (4) Anticipated normal particulate matter emission levels; and (B) Submit the test plan to the Administrator for approval at least 90 calendar days before the correlation test is scheduled to be conducted. (iv) The Administrator will review and approve/disapprove the correlation [[Page 22]] test plan under the procedures for review and approval of the site- specific test plan provided by Sec. 63.7(c)(3)(i) and (iii). If the Administrator fails to approve or disapprove the correlation test plan within the time period specified by Sec. 63.7(c)(3)(i), the plan is considered approved, unless the Administrator has requested additional information. (v) The particulate matter and opacity standards and associated operating limits and conditions will not be waived for more than 96 hours, in the aggregate, for a correlation test, including all runs of all test conditions, unless more time is approved by the Administrator. (vi) The stack sampling team must be on-site and prepared to perform correlation testing no later than 24 hours after you modify operations to attain the desired particulate matter emissions concentrations, unless you document in the correlation test plan that a longer period of conditioning is appropriate. (vii) You must return to operating conditions indicative of compliance with the applicable particulate matter and opacity standards as soon as possible after correlation testing is completed. (9) Alternative standards for existing or new hazardous waste burning lightweight aggregate kilns using MACT. (i) You may petition the Administrator to recommend alternative semivolatile metal, low volatile metal, mercury, or hydrochloric acid/chlorine gas emission standards if: (A) You cannot achieve one or more of these standards while using maximum achievable control technology (MACT) because of the raw material contribution to emissions of the regulated metals or hydrochloric acid/ chlorine gas; or (B) You determine that mercury is not present at detectable levels in your raw material. (ii) The alternative standard that you recommend under paragraph (b)(9)(i)(A) of this section may be an operating requirement, such as a hazardous waste feedrate limitation for metals and/or chlorine, and/or an emission limitation. (iii) The alternative standard must include a requirement to use MACT, or better, applicable to the standard for which the source is seeking relief, as defined in paragraphs (b)(9)(viii) and (ix) of this section. (iv) Documentation required. (A) The alternative standard petition you submit under paragraph (b)(9)(i)(A) of this section must include data or information documenting that raw material contributions to emissions of the regulated metals or hydrochloric acid/chlorine gas prevent you from complying with the emission standard even though the source is using MACT, as defined in paragraphs (b)(9)(viii) and (ix) of this section, for the standard for which you are seeking relief. (B) Alternative standard petitions that you submit under paragraph (b)(9)(i)(B) of this section must include data or information documenting that mercury is not present at detectable levels in raw materials. (v) You must include data or information with semivolatile metal and low volatility metal alternative standard petitions that you submit under paragraph (b)(9)(i)(A) of this section documenting that increased chlorine feedrates associated with the burning of hazardous waste, when compared to non-hazardous waste operations, do not significantly increase metal emissions attributable to raw materials. (vi) You must include data or information with semivolatile metal, low volatile metal, and hydrochloric acid/chlorine gas alternative standard petitions that you submit under paragraph (b)(9)(i)(A) of this section documenting that semivolatile metal, low volatile metal, and hydrochloric acid/chlorine gas emissions attributable to the hazardous waste only will not exceed the emission standards in Sec. 63.1205(a) and (b). (vii) You must not operate pursuant to your recommended alternative standards in lieu of emission standards specified in Sec. 63.1205(a) and (b): (A) Unless the Administrator approves the provisions of the alternative standard petition request or establishes other alternative standards; and (B) Until you submit a revised Notification of Compliance that incorporates the revised standards. [[Page 23]] (viii) For purposes of this alternative standard provision, MACT for existing hazardous waste burning lightweight aggregate kilns is defined as: (A) For mercury, a hazardous waste feedrate corresponding to an MTEC of 24[mu]g/dscm or less; (B) For semivolatile metals, a hazardous waste feedrate corresponding to an MTEC of 280,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 57 mg/dscm or less; (C) For low volatile metals, a hazardous waste feedrate corresponding to an MTEC of 120,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 57 mg/dscm or less; and (D) For hydrochloric acid/chlorine gas, a hazardous waste chlorine feedrate corresponding to an MTEC of 2,000,000 [mu]g/dscm or less, and use of an air pollution control device with a hydrochloric acid/chlorine gas removal efficiency of 85 percent or greater. (ix) For purposes of this alternative standard provision, MACT for new hazardous waste burning lightweight aggregate kilns is defined as: (A) For mercury, a hazardous waste feedrate corresponding to an MTEC of 4 [mu]g/dscm or less; (B) For semivolatile metals, a hazardous waste feedrate corresponding to an MTEC of 280,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 57 mg/dscm or less; (C) For low volatile metals, a hazardous waste feedrate corresponding to an MTEC of 46,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 57 mg/dscm or less; (D) For hydrochloric acid/chlorine gas, a hazardous waste chlorine feedrate corresponding to an MTEC of 14,000,000 [mu]g/dscm or less, and use of a wet scrubber with a hydrochloric acid/chlorine gas removal efficiency of 99.6 percent or greater. (10) Alternative standards for existing or new hazardous waste burning cement kilns using MACT. (i) You may petition the Administrator to recommend alternative semivolatile, low volatile metal, mercury, and/ or hydrochloric acid/chlorine gas emission standards if: (A) You cannot achieve one or more of these standards while using maximum achievable control technology (MACT) because of raw material contributions to emissions of the regulated metals or hydrochloric acid/ chlorine gas; or (B) You determine that mercury is not present at detectable levels in your raw material. (ii) The alternative standard that you recommend under paragraph (b)(10)(i)(A) of this section may be an operating requirement, such as a hazardous waste feedrate limitation for metals and/or chlorine, and/or an emission limitation. (iii) The alternative standard must include a requirement to use MACT, or better, applicable to the standard for which the source is seeking relief, as defined in paragraphs (b)(10)(viii) and (ix) of this section. (iv) Documentation required. (A) The alternative standard petition you submit under paragraph (b)(10)(i)(A) of this section must include data or information documenting that raw material contributions to emissions prevent you from complying with the emission standard even though the source is using MACT, as defined in paragraphs (b)(10)(viii) and (ix) of this section, for the standard for which you are seeking relief. (B) Alternative standard petitions that you submit under paragraph (b)(10)(i)(B) of this section must include data or information documenting that mercury is not present at detectable levels in raw materials. (v) You must include data or information with semivolatile metal and low volatile metal alternative standard petitions that you submit under paragraph (b)(10)(i)(A) of this section documenting that increased chlorine feedrates associated with the burning of hazardous waste, when compared to non-hazardous waste operations, do not significantly increase metal emissions attributable to raw materials. (vi) You must include data or information with semivolatile metal, low volatile metal, and hydrochloric acid/chlorine gas alternative standard petitions that you submit under paragraph (b)(10)(i)(A) of this section documenting that emissions of the regulated metals and hydrochloric acid/ [[Page 24]] chlorine gas attributable to the hazardous waste only will not exceed the emission standards in Sec. 63.1204(a) and (b). (vii) You must not operate pursuant to your recommended alternative standards in lieu of emission standards specified in Sec. 63.1204(a) and (b): (A) Unless the Administrator approves the provisions of the alternative standard petition request or establishes other alternative standards; and (B) Until you submit a revised Notification of Compliance that incorporates the revised standards. (viii) For purposes of this alternative standard provision, MACT for existing hazardous waste burning cement kilns is defined as: (A) For mercury, a hazardous waste feedrate corresponding to an MTEC of 88[mu]g/dscm or less; (B) For semivolatile metals, a hazardous waste feedrate corresponding to an MTEC of 31,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 0.15 kg/Mg dry feed or less; (C) For low volatile metals, a hazardous waste feedrate corresponding to an MTEC of 54,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 0.15 kg/Mg dry feed or less; and (D) For hydrochloric acid/chlorine gas, a hazardous waste chlorine feedrate corresponding to an MTEC of 720,000 [mu]g/dscm or less. (ix) For purposes of this alternative standard provision, MACT for new hazardous waste burning cement kilns is defined as: (A) For mercury, a hazardous waste feedrate corresponding to an MTEC of 7 [mu]g/dscm or less; (B) For semivolatile metals, a hazardous waste feedrate corresponding to an MTEC of 31,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 0.15 kg/Mg dry feed or less; (C) For low volatile metals, a hazardous waste feedrate corresponding to an MTEC of 15,000 [mu]g/dscm or less, and use of a particulate matter control device that achieves particulate matter emissions of 0.15 kg/Mg dry feed or less; (D) For hydrochloric acid/chlorine gas, a hazardous waste chlorine feedrate corresponding to an MTEC of 420,000 [mu]g/dscm or less. (11) Calculation of hazardous waste residence time. You must calculate the hazardous waste residence time and include the calculation in the performance test plan under Sec. 63.1207(f) and the operating record. You must also provide the hazardous waste residence time in the Documentation of Compliance under Sec. 63.1211(c) and the Notification of Compliance under Secs. 63.1207(j) and 63.1210(b). (12) Documenting compliance with the standards based on performance testing. (i) You must conduct a minimum of three runs of a performance test required under Sec. 63.1207 to document compliance with the emission standards of this subpart. (ii) You must document compliance with the emission standards based on the arithmetic average of the emission results of each run, except that you must document compliance with the destruction and removal efficiency standard for each run of the comprehensive performance test individually. (13) Cement kilns and lightweight aggregate kilns that feed hazardous waste at a location other than the end where products are normally discharged and where fuels are normally fired. (i) Cement kilns that feed hazardous waste at a location other than the end where products are normally discharged and where fuels are normally fired must comply with the carbon monoxide and hydrocarbon standards of Sec. 63.1204 as follows: (A) For existing sources, you must not discharge or cause combustion gases to be emitted into the atmosphere that contain either: (1) Hydrocarbons in the main stack in excess of 20 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; or (2) Hydrocarbons both in the by-pass duct and at a preheater tower combustion gas monitoring location in excess of 10 parts per million by volume, at each location, over an hourly rolling [[Page 25]] average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; or (3) If the only firing location of hazardous waste upstream (in terms of gas flow) of the point where combustion gases are diverted into the bypass duct is at the kiln end where products are normally discharged, then both hydrocarbons at the preheater tower combustion gas monitoring location in excess of 10 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, and either hydrocarbons in the by-pass duct in excess of 10 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, or carbon monoxide in excess of 100 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, and corrected to 7 percent oxygen. If you comply with the carbon monoxide standard of 100 parts per million by volume in the by-pass duct, then you must also not discharge or cause combustion gases to be emitted into the atmosphere that contain hydrocarbons in the by-pass duct in excess of 10 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, at any time during the destruction and removal efficiency (DRE) test runs or their equivalent as provided by Sec. 63.1206(b)(7). (B) For new sources, you must not discharge or cause combustion gases to be emitted into the atmosphere that contain either: (1) Hydrocarbons in the main stack in excess of 20 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; or (2)(i) Hydrocarbons both in the by-pass duct and at a preheater tower combustion gas monitoring location in excess of 10 parts per million by volume, at each location, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, and (ii) Hydrocarbons in the main stack, if construction of the kiln commenced after April 19, 1996 at a plant site where a cement kiln (whether burning hazardous waste or not) did not previously exist, to 50 parts per million by volume, over a 30-day block average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane; or (3)(i) If the only firing location of hazardous waste upstream (in terms of gas flow) of the point where combustion gases are diverted into the bypass duct is at the kiln end where products are normally discharged, then both hydrocarbons at the preheater tower combustion gas monitoring location in excess of 10 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, and either hydrocarbons in the by-pass duct in excess of 10 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, or carbon monoxide in excess of 100 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, and corrected to 7 percent oxygen. If you comply with the carbon monoxide standard of 100 parts per million by volume in the by-pass duct, then you must also not discharge or cause combustion gases to be emitted into the atmosphere that contain hydrocarbons in the by-pass duct in excess of 10 parts per million by volume, over an hourly rolling average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane, at any time [[Page 26]] during the destruction and removal efficiency (DRE) test runs or their equivalent as provided by Sec. 63.1206(b)(7). (ii) If construction of the kiln commenced after April 19, 1996 at a plant site where a cement kiln (whether burning hazardous waste or not) did not previously exist, hydrocarbons are limited to 50 parts per million by volume, over a 30-day block average (monitored continuously with a continuous emissions monitoring system), dry basis, corrected to 7 percent oxygen, and reported as propane. (ii) Lightweight aggregate kilns that feed hazardous waste at a location other than the end where products are normally discharged and where fuels are normally fired must comply with the hydrocarbon standards of Sec. 63.1205 as follows: (A) Existing sources must comply with the 20 parts per million by volume hydrocarbon standard under Sec. 63.1205(a)(5)(ii); (B) New sources must comply with the 20 parts per million by volume hydrocarbon standard under Sec. 63.1205(b)(5)(ii). (14) Alternative to the particulate matter standard for incinerators. (i) General. In lieu of complying with the applicable particulate matter standard of Sec. 63.1203(a)(7) or (b)(7), existing and new incinerators may elect to instead comply with the alternative metal emission control requirements described in paragraph (b)(14)(ii) or (b)(14)(iii) of this section, respectively. (ii) Alternative metal emission control requirements for existing incinerators. (A) You must not discharge or cause combustion gases to be emitted into the atmosphere that contain lead, cadmium, and selenium in excess of 240 [mu]g/dscm, combined emissions, corrected to 7 percent oxygen; and, (B) You must not discharge or cause combustion gases to be emitted into the atmosphere that contain arsenic, beryllium, chromium, antimony, cobalt, manganese, and nickel in excess of 97 [mu]g/dscm, combined emissions, corrected to 7 percent oxygen; and, (C) You must comply with the provisions specified in paragraph (b)(14)(iv) of this section. (iii) Alternative metal emission control requirements for new incinerators. (A) You must not discharge or cause combustion gases to be emitted into the atmosphere that contain lead, cadmium, and selenium in excess of 24 [mu]g/dscm, combined emissions, corrected to 7 percent oxygen; and, (B) You must not discharge or cause combustion gases to be emitted into the atmosphere that contain arsenic, beryllium, chromium, antimony, cobalt, manganese, and nickel in excess of 97 [mu]g/dscm, combined emissions, corrected to 7 percent oxygen; and, (C) You must comply with the provisions specified in paragraph (b)(14)(iv) of this section. (iv) Other requirements. Existing and new incinerators must document in the operating record that they meet the requirements of paragraph (b)(14)(iv)(A) through (C) of this section. (A) The twelve-hour rolling average of the maximum theoretical emissions concentration for lead, cadmium, and selenium, combined, for the combined hazardous waste feedstreams to the incinerator, must not exceed: (1) For existing incinerators, 1,325 [mu]g/dscm. (2) For new incinerators, 875 [mu]g/dscm. (B) The twelve-hour rolling average of the maximum theoretical emissions concentration for arsenic, beryllium, chromium, antimony, cobalt, manganese, and nickel, combined, for the combined hazardous waste feedstreams to the incinerator, must not exceed: (1) For existing incinerators, 6,000 [mu]g/dscm. (2) For new incinerators, 3250 [mu]g/dscm. (C) You must document that your air pollution control system achieves at least a 90 percent system removal efficiency for semivolatile metals. In making this demonstration, you may spike semivolatile metals above the applicable levels of paragraph (b)(14)(iv)(A) or (B) of this section provided that the applicable alternative emission limitation of paragraph (b)(14)(ii)(A) or (iii)(A) of this section is attained during the test. This test may be performed independently of the comprehensive performance test and must be used to establish applicable operating parameter limits as described in Sec. 63.1209(n), not including Sec. 63.1209(n)(2), to ensure that a 90 percent semivolatile [[Page 27]] metal system removal efficiency is achieved during normal operations. (v) Operating limits. (A) Semivolatile and low volatile metal operating parameter limits must be established to ensure compliance with the alternative emission limitations described in paragraphs (b)(14)(ii) and (iii) of this section pursuant to Sec. 63.1209(n), except that semivolatile metal feedrate limits would apply to lead, cadmium, and selenium, combined, and low volatile metal feedrate limits would apply to arsenic, beryllium, chromium, antimony, cobalt, manganese, and nickel, combined. (B) Twelve-hour rolling average hazardous waste metal feedrate limits required pursuant to paragraphs (b)(14)(iv)(A) and (B) of this section are based on the combined hazardous waste feedstreams to the incinerator and may be expressed either as an maximum theoretical emission concentration limit or as a restriction on maximum hazardous waste metals mass feedrate and minimum gas flow rate. (C) For purposes of complying with the twelve-hour rolling average hazardous waste metal feedrate limits of paragraphs (b)(14)(iv)(A) and (B) of this section, non-detectable metal constituents in each hazardous waste feed must be assumed to be present at one-half the detection limit. (15) Alternative to the interim standards for mercury for cement and lightweight aggregate kilns. (i) General. In lieu of complying with the applicable mercury standards of Secs. 63.1204(a)(2) and (b)(2) for existing and new cement kilns and Secs. 63.1205(a)(2) and (b)(2) for existing and new lightweight aggregate kilns, you may instead elect to comply with the alternative mercury standard described in paragraphs (b)(15)(ii) through (b)(15)(v) of this section. (ii) Operating requirement. You must not exceed a hazardous waste feedrate corresponding to a maximum theoretical emission concentration (MTEC) of 120 [mgr]g/dscm on a twelve-hour rolling average. (iii) To document compliance with the operating requirement of paragraph (b)(15)(ii) of this section, you must: (A) Monitor and record the feedrate of mercury for each hazardous waste feedstream according to Sec. 63.1209(c); (B) Monitor with a CMS and record in the operating record the gas flowrate (either directly or by monitoring a surrogate parameter that you have correlated to gas flowrate); (C) Continuously calculate and record in the operating record a MTEC assuming mercury from all hazardous waste feedstreams is emitted; (D) Interlock the MTEC calculated in paragraph (b)(15)(iii)(C) of this section to the AWFCO system to stop hazardous waste burning when the MTEC exceeds the operating requirement of paragraph (b)(15)(ii) of this section. (iv) In lieu of the requirement in paragraph (b)(15)(iii) of this section, you may: (A) Identify in the Notification of Compliance a minimum gas flowrate limit and a maximum feedrate limit of mercury from all hazardous waste feedstreams that ensures the MTEC calculated in paragraph (b)(15)(iii)(C) of this section is below the operating requirement of paragraph (b)(15)(ii) of this section; and (B) Interlock the minimum gas flowrate limit and maximum feedrate limits in paragraph (b)(15)(iv)(A) of this section to the AWFCO system to stop hazardous waste burning when the gas flowrate or mercury feedrate exceeds the limits in paragraph (b)(15)(iv)(A) of this section. (v) Notification requirement. You must notify in writing the RCRA authority that you intend to comply with the alternative standard. (c) Operating requirements--(1) General. (i) You must operate only under the operating requirements specified in the Documentation of Compliance under Sec. 63.1211(c) or the Notification of Compliance under Secs. 63.1207(j) and 63.1210(b), except: (A) During performance tests under approved test plans according to Sec. 63.1207(e), (f), and (g), and (B) Under the conditions of paragraph (b)(1)(i) or (ii) of this section; (ii) The Documentation of Compliance and the Notification of Compliance must contain operating requirements including, but not limited to, [[Page 28]] the operating requirements in this section and Sec. 63.1209 (iii) Failure to comply with the operating requirements is failure to ensure compliance with the emission standards of this subpart; (iv) Operating requirements in the Notification of Compliance are applicable requirements for purposes of parts 70 and 71 of this chapter; (v) The operating requirements specified in the Notification of Compliance will be incorporated in the title V permit. (2) Startup, shutdown, and malfunction plan. (i) You are subject to the startup, shutdown, and malfunction plan requirements of Sec. 63.6(e)(3). (ii) If you elect to comply with Secs. 270.235(a)(1)(iii), 270.235(a)(2)(iii), or 270.235(b)(1)(ii) of this chapter to address RCRA concerns that you minimize emissions of toxic compounds from startup, shutdown, and malfunction events (including releases from emergency safety vents): (A) The startup, shutdown, and malfunction plan must include a description of potential causes of malfunctions, including releases from emergency safety vents, that may result in significant releases of hazardous air pollutants, and actions the source is taking to minimize the frequency and severity of those malfunctions. (B) You must submit the startup, shutdown, and malfunction plan to the Administrator for review and approval. (1) Approval procedure. The Administrator will notify you of approval or intention to deny approval of the startup, shutdown, and malfunction plan within 90 calendar days after receipt of the original request and within 60 calendar days after receipt of any supplemental information that you submit. Before disapproving the plan, the Administrator will notify you of the Administrator's intention to disapprove the plan together with: (i) Notice of the information and findings on which intended disapproval is based; and (ii) Notice of opportunity for you to present additional information to the Administrator before final action on disapproval of the plan. At the time the Administrator notifies you of intention to disapprove the plan, the Administrator will specify how much time you will have after being notified on the intended disapproval to submit additional information. (2) Responsibility of owners and operators. You are responsible for ensuring that you submit any supplementary and additional information supporting your plan in a timely manner to enable the Administrator to consider whether to approve the plan. Neither your submittal of the plan, nor the Administrator's failure to approve or disapprove the plan, relieves you of the responsibility to comply with the provisions of this subpart. (C) Changes to the plan that may significantly increase emissions. (1) You must request approval in writing from the Administrator within 5 days after making a change to the startup, shutdown, and malfunction plan that may significantly increase emissions of hazardous air pollutants. (2) To request approval of such changes to the startup, shutdown, and malfunction plan, you must follow the procedures provided by paragraph (c)(2)(ii)(B) of this section for initial approval of the plan. (iii) You must identify in the plan a projected oxygen correction factor based on normal operations to use during periods of startup and shutdown. (iv) You must record the plan in the operating record. (v) Operating under the startup, shutdown, and malfunction plan. (A) Compliance with AWFCO requirements during malfunctions. (1) During malfunctions, the automatic waste feed cutoff requirements of Sec. 63.1206(c)(3) continue to apply, except for paragraphs (c)(3)(v) and (c)(3)(vi) of this section. If you exceed a part 63, Subpart EEE, of this chapter emission standard monitored by a CEMS or COMs or operating limit specified under Sec. 63.1209, the automatic waste feed cutoff system must immediately and automatically cutoff the hazardous waste feed, except as provided by paragraph (c)(3)(viii) of this section. If the malfunction itself prevents immediate and automatic cutoff of the hazardous waste feed, however, you must cease feeding hazardous waste as quickly as possible. (2) Although the automatic waste feed cutoff requirements continue to [[Page 29]] apply during a malfunction, an exceedance of an emission standard monitored by a CEMS or COMS or operating limit specified under Sec. 63.1209 is not a violation of this subpart if you take the corrective measures prescribed in the startup, shutdown, and malfunction plan. (3) Excessive exceedances during malfunctions. For each set of 10 exceedances of an emission standard or operating requirement while hazardous waste remains in the combustion chamber (i.e., when the hazardous waste residence time has not transpired since the hazardous waste feed was cutoff) during a 60-day block period, you must: (i) Within 45 days of the 10th exceedance, complete an investigation of the cause of each exceedance and evaluation of approaches to minimize the frequency, duration, and severity of each exceedance, and revise the startup, shutdown, and malfunction plan as warranted by the evaluation to minimize the frequency, duration, and severity of each exceedance; and (ii) Record the results of the investigation and evaluation in the operating record, and include a summary of the investigation and evaluation, and any changes to the startup, shutdown, and malfunction plan, in the excess emissions report required under Sec. 63.10(e)(3). (B) Compliance with AWFCO requirements when burning hazardous waste during startup and shutdown. (1) If you feed hazardous waste during startup or shutdown, you must include waste feed restrictions (e.g., type and quantity), and other appropriate operating conditions and limits in the startup, shutdown, and malfunction plan. (2) You must interlock the operating limits you establish under paragraph (c)(2)(v)(B)(1) of this section with the automatic waste feed cutoff system required under Sec. 63.1206(c)(3), except for paragraphs (c)(3)(v) and (c)(3)(vi) of this section. (3) When feeding hazardous waste during startup or shutdown, the automatic waste feed cutoff system must immediately and automatically cutoff the hazardous waste feed if you exceed the operating limits you establish under paragraph (c)(2)(v)(B)(1) of this section, except as provided by paragraph (c)(3)(viii) of this section. (4) Although the automatic waste feed cutoff requirements of this paragraph apply during startup and shutdown, an exceedance of an emission standard or operating limit is not a violation of this subpart if you comply with the operating procedures prescribed in the startup, shutdown, and malfunction plan. (3) Automatic waste feed cutoff (AWFCO)--(i) General. Upon the compliance date, you must operate the hazardous waste combustor with a functioning system that immediately and automatically cuts off the hazardous waste feed, except as provided by paragraph (c)(3)(viii) of this section: (A) When any of the following are exceeded: Operating parameter limits specified under Sec. 63.1209; an emission standard monitored by a CEMS; and the allowable combustion chamber pressure; (B) When the span value of any CMS detector, except a CEMS, is met or exceeded; (C) Upon malfunction of a CMS monitoring an operating parameter limit specified under Sec. 63.1209 or an emission level; or (D) When any component of the automatic waste feed cutoff system fails. (ii) Ducting of combustion gases. During an AWFCO, you must continue to duct combustion gasses to the air pollution control system while hazardous waste remains in the combustion chamber (i.e., if the hazardous waste residence time has not transpired since the hazardous waste feed cutoff system was activated). (iii) Restarting waste feed. You must continue to monitor during the cutoff the operating parameters for which limits are established under Sec. 63.1209 and the emissions required under that section to be monitored by a CEMS, and you must not restart the hazardous waste feed until the operating parameters and emission levels are within the specified limits. (iv) Failure of the AWFCO system. If the AWFCO system fails to automatically and immediately cutoff the flow of hazardous waste upon exceedance of parameter required to be interlocked [[Page 30]] with the AWFCO system under paragraph (c)(3)(i) of this section, you have failed to comply with the AWFCO requirements of paragraph (c)(3) of this section. (v) Corrective measures. If, after any AWFCO, there is an exceedance of an emission standard or operating requirement, irrespective of whether the exceedance occurred while hazardous waste remained in the combustion chamber (i.e., whether the hazardous waste residence time has transpired since the hazardous waste feed cutoff system was activated), you must investigate the cause of the AWFCO, take appropriate corrective measures to minimize future AWFCOs, and record the findings and corrective measures in the operating record. (vi) Excessive exceedance reporting. (A) For each set of 10 exceedances of an emission standard or operating requirement while hazardous waste remains in the combustion chamber (i.e., when the hazardous waste residence time has not transpired since the hazardous waste feed was cutoff) during a 60-day block period, you must submit to the Administrator a written report within 5 calendar days of the 10th exceedance documenting the exceedances and results of the investigation and corrective measures taken. (B) On a case-by-case basis, the Administrator may require excessive exceedance reporting when fewer than 10 exceedances occur during a 60- day block period. (vii) Testing. The AWFCO system and associated alarms must be tested at least weekly to verify operability, unless you document in the operating record that weekly inspections will unduly restrict or upset operations and that less frequent inspection will be adequate. At a minimum, you must conduct operability testing at least monthly. You must document and record in the operating record AWFCO operability test procedures and results. (viii) Ramping down waste feed. (A) You may ramp down the waste feedrate of pumpable hazardous waste over a period not to exceed one minute, except as provided by paragraph (c)(3)(viii)(B) of this section. If you elect to ramp down the waste feed, you must document ramp down procedures in the operating and maintenance plan. The procedures must specify that the ramp down begins immediately upon initiation of automatic waste feed cutoff and the procedures must prescribe a bona fide ramping down. If an emission standard or operating limit is exceeded during the ramp down, you have failed to comply with the emission standards or operating requirements of this subpart. (B) If the automatic waste feed cutoff is triggered by an exceedance of any of the following operating limits, you may not ramp down the waste feed cutoff: Minimum combustion chamber temperature, maximum hazardous waste feedrate, or any hazardous waste firing system operating limits that may be established for your combustor. (4) ESV openings--(i) Failure to meet standards. If an emergency safety vent (ESV) opens when hazardous waste remains in the combustion chamber (i.e., when the hazardous waste residence time has not expired) during an event other than a malfunction as defined in the startup, shutdown, and malfunction plan such that combustion gases are not treated as during the most recent comprehensive performance test (e.g., if the combustion gas by-passes any emission control device that was operating during the performance test), you must document in the operating record whether you remain in compliance with the emission standards of this subpart considering emissions during the ESV opening event. (ii) ESV operating plan. (A) You must develop an ESV operating plan, comply with the operating plan, and keep the plan in the operating record. (B) The ESV operating plan must provide detailed procedures for rapidly stopping the waste feed, shutting down the combustor, and maintaining temperature and negative pressure in the combustion chamber during the hazardous waste residence time, if feasible. The plan must include calculations and information and data documenting the effectiveness of the plan's procedures for ensuring that combustion chamber temperature and negative pressure are maintained as is reasonably feasible. (iii) Corrective measures. After any ESV opening that results in a failure [[Page 31]] to meet the emission standards as defined in paragraph (c)(4)(i) of this section, you must investigate the cause of the ESV opening, take appropriate corrective measures to minimize such future ESV openings, and record the findings and corrective measures in the operating record. (iv) Reporting requirements. You must submit to the Administrator a written report within 5 days of an ESV opening that results in failure to meet the emission standards of this subpart (as determined in paragraph (c)(4)(i) of this section) documenting the result of the investigation and corrective measures taken. (5) Combustion system leaks. (i) Combustion system leaks of hazardous air pollutants must be controlled by: (A) Keeping the combustion zone sealed to prevent combustion system leaks; or (B) Maintaining the maximum combustion zone pressure lower than ambient pressure using an instantaneous monitor; or (C) Upon prior written approval of the Administrator, an alternative means of control to provide control of combustion system leaks equivalent to maintenance of combustion zone pressure lower than ambient pressure; or (D) Upon prior written approval of the Administrator, other technique(s) which can be demonstrated to prevent fugitive emissions without use of instantaneous pressure limits; and (ii) You must specify in the performance test workplan and Notification of Compliance the method that will be used to control combustion system leaks. If you control combustion system leaks by maintaining the combustion zone pressure lower than ambient pressure using an instantaneous monitor, you must also specify in the performance test workplan and Notification of Compliance the monitoring and recording frequency of the pressure monitor, and specify how the monitoring approach will be integrated into the automatic waste feed cutoff system. (6) Operator training and certification. (i) You must establish training programs for all categories of personnel whose activities may reasonably be expected to directly affect emissions of hazardous air pollutants from the source. Such persons include, but are not limited to, chief facility operators, control room operators, continuous monitoring system operators, persons that sample and analyze feedstreams, persons that manage and charge feedstreams to the combustor, persons that operate emission control devices, and ash and waste handlers. Each training program shall be of a technical level commensurate with the person's job duties specified in the training manual. Each commensurate training program shall require an examination to be administered by the instructor at the end of the training course. Passing of this test shall be deemed the ``certification'' for personnel, except that, for control room operators, the training and certification program shall be as specified in paragraphs (c)(6)(iii) through (c)(6)(vi) of this section. (ii) You must ensure that the source is operated and maintained at all times by persons who are trained and certified to perform these and any other duties that may affect emissions of hazardous air pollutants. A certified control room operator must be on duty at the site at all times the source is in operation. (iii) Hazardous waste incinerator control room operators must: (A) Be trained and certified under a site-specific, source-developed and implemented program that meets the requirements of paragraph (c)(6)(v) of this section; or (B) Be trained under the requirements of, and certified under, the American Society of Mechanical Engineers Standard Number QHO-1-1994 and QHO-1a-1996 Addenda (incorporated by reference--see Sec. 63.14(e)). If you choose to use the ASME program: (1) Control room operators must, prior to the compliance date, achieve provisional certification, and must submit an application to ASME and be scheduled for the full certification exam. Within one year of the compliance date, control room operators must achieve full certification; (2) New operators and operators of new sources must, before assuming [[Page 32]] their duties, achieve provisional certification, and must submit an application to ASME, and be scheduled for the full certification exam. Within one year of assuming their duties, these operators must achieve full certification; or (C) Be trained and certified under a State program. (iv) Cement kiln and lightweight aggregate kiln control room operators must be trained and certified under: (A) A site-specific, source-developed and implemented program that meets the requirements of paragraph (c)(6)(v) of this section; or (B) A State program. (v) Site-specific, source developed and implemented training programs for control room operators must include the following elements: (A) Training on the following subjects: (1) Environmental concerns, including types of emissions; (2) Basic combustion principles, including products of combustion; (3) Operation of the specific type of combustor used by the operator, including proper startup, waste firing, and shutdown procedures; (4) Combustion controls and continuous monitoring systems; (5) Operation of air pollution control equipment and factors affecting performance; (6) Inspection and maintenance of the combustor, continuous monitoring systems, and air pollution control devices; (7) Actions to correct malfunctions or conditions that may lead to malfunction; (8) Residue characteristics and handling procedures; and (9) Applicable Federal, state, and local regulations, including Occupational Safety and Health Administration workplace standards; and (B) An examination designed and administered by the instructor; and (C) Written material covering the training course topics that may serve as reference material following completion of the course. (vi) To maintain control room operator qualification under a site- specific, source developed and implemented training program as provided by paragraph (c)(6)(v) of this section, control room operators must complete an annual review or refresher course covering, at a minimum, the following topics: (A) Update of regulations; (B) Combustor operation, including startup and shutdown procedures, waste firing, and residue handling; (C) Inspection and maintenance; (D) Responses to malfunctions or conditions that may lead to malfunction; and (E) Operating problems encountered by the operator. (vii) You must record the operator training and certification program in the operating record. (7) Operation and maintenance plan--(i) General. (A) You must prepare and at all times operate according to an operation and maintenance plan that describes in detail procedures for operation, inspection, maintenance, and corrective measures for all components of the combustor, including associated pollution control equipment, that could affect emissions of regulated hazardous air pollutants. (B) The plan must prescribe how you will operate and maintain the combustor in a manner consistent with good air pollution control practices for minimizing emissions at least to the levels achieved during the comprehensive performance test. (C) This plan ensures compliance with the operation and maintenance requirements of Sec. 63.6(e) and minimizes emissions of pollutants, automatic waste feed cutoffs, and malfunctions. (D) You must record the plan in the operating record. (ii) Bag leak detection system requirements for baghouses at lightweight aggregate kilns and incinerators. If you own or operate a hazardous waste incinerator or hazardous waste burning lightweight aggregate kiln equipped with a baghouse (fabric filter), you must continuously operate a bag leak detection system that meets the specifications and requirements of paragraph (c)(7)(ii)(A) of this section and you must comply with the corrective measures requirements of paragraph (c)(7)(ii)(B) of this section: (A) Bag leak detection system specification and requirements. (1) The bag leak detection system must be certified by [[Page 33]] the manufacturer to be capable of continuously detecting and recording particulate matter emissions at concentrations of 1.0 milligrams per actual cubic meter unless you demonstrate, pursuant to procedures in Sec. 63.1209(a)(1), that a higher sensitivity would adequately detect bag leaks; (2) The bag leak detection system shall provide output of relative particulate matter loadings; (3) The bag leak detection system shall be equipped with an alarm system that will sound an audible alarm when an increase in relative particulate loadings is detected over a preset level; (4) The bag leak detection system shall be installed and operated in a manner consistent with available written guidance from the U.S. Environmental Protection Agency or, in the absence of such written guidance, the manufacturer's written specifications and recommendations for installation, operation, and adjustment of the system; (5) The initial adjustment of the system shall, at a minimum, consist of establishing the baseline output by adjusting the sensitivity (range) and the averaging period of the device, and establishing the alarm set points and the alarm delay time; (6) Following initial adjustment, you must not adjust the sensitivity or range, averaging period, alarm set points, or alarm delay time, except as detailed in the operation and maintenance plan required under paragraph (c)(7)(i) of this section. You must not increase the sensitivity by more than 100 percent or decrease the sensitivity by more than 50 percent over a 365 day period unless such adjustment follows a complete baghouse inspection which demonstrates the baghouse is in good operating condition; (7) For negative pressure or induced air baghouses, and positive pressure baghouses that are discharged to the atmosphere through a stack, the bag leak detector shall be installed downstream of the baghouse and upstream of any wet acid gas scrubber; and (8) Where multiple detectors are required, the system's instrumentation and alarm system may be shared among the detectors. (B) Bag leak detection system corrective measures requirements. The operating and maintenance plan required by paragraph (c)(7)(i) of this section must include a corrective measures plan that specifies the procedures you will follow in the case of a bag leak detection system alarm. The corrective measures plan must include, at a minimum, the procedures used to determine and record the time and cause of the alarm as well as the corrective measures taken to correct the control device malfunction or minimize emissions as specified below. Failure to initiate the corrective measures required by this paragraph is failure to ensure compliance with the emission standards in this subpart. (1) You must initiate the procedures used to determine the cause of the alarm within 30 minutes of the time the alarm first sounds; and (2) You must alleviate the cause of the alarm by taking the necessary corrective measure(s) which may include, but are not to be limited to, the following measures: (i) Inspecting the baghouse for air leaks, torn or broken filter elements, or any other malfunction that may cause an increase in emissions; (ii) Sealing off defective bags or filter media; (iii) Replacing defective bags or filter media, or otherwise repairing the control device; (iv) Sealing off a defective baghouse compartment; (v) Cleaning the bag leak detection system probe, or otherwise repairing the bag leak detection system; or (vi) Shutting down the combustor. [64 FR 53038, Sept. 30, 1999, as amended at 65 FR 42298, July 10, 2000; 65 FR 67271, Nov. 9, 2000; 66 FR 24272, May 14, 2001; 66 FR 35103, July 3, 2001; 66 FR 63317, Dec. 7, 2001; 67 FR 6813, Feb. 13, 2002; 67 FR 6989, Feb. 14, 2002; 67 FR 77691, Dec. 19, 2002]