[Code of Federal Regulations]
[Title 40, Volume 14]
[Revised as of July 1, 2003]
From the U.S. Government Printing Office via GPO Access
[CITE: 40CFR79.57]

[Page 518-526]
 
                   TITLE 40--PROTECTION OF ENVIRONMENT
 
         CHAPTER I--ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)
 
PART 79--REGISTRATION OF FUELS AND FUEL ADDITIVES--Table of Contents
 
            Subpart F--Testing Requirements for Registration
 
Sec. 79.57  Emission generation.

    This section specifies the equipment and procedures that must be 
used in generating the emissions which are to be subjected to the 
characterization procedures and/or the biological tests specified in 
Secs. 79.52(b) and 79.53 of these regulations. When applicable, they may 
also be required in conjunction with testing under Secs. 79.54 and 
79.58(c). Additional requirements concerning emission generation, 
delivery, dilution, quality control, and safety practices are outlined 
in Sec. 79.61.
    (a) Vehicle and engine selection criteria. (1) All vehicles and 
engines used to generate emissions for testing a fuel or additive/fuel 
mixture must be new (i.e., never before titled) and placed into the 
program with less than 500 miles on the odometer or 12 hours on the 
engine chronometer. The vehicles and engines shall be unaltered from the 
specifications of the original equipment manufacturer.
    (2) The vehicle/engine type, vehicle/engine class, and vehicle/
engine subclass designated to generate emissions for a given fuel or 
additive shall be the same type, class, and subclass which, over the 
previous three years, has consumed the most gallons of fuel in the fuel 
family applicable to the given fuel or additive. No distinction shall be 
made between light-duty vehicles and light-duty trucks for purposes of 
this classification.
    (3) Within this vehicle/engine type, class, and subclass, the 
specific vehicles and engines acceptable for emission generation are 
those that represent the most common fuel metering system and the most 
common of the most important emission control system devices or 
characteristics with respect to emission reduction performance for the 
model year in which testing begins. These vehicles will be determined 
through a survey of the previous model year's vehicle/engine sales 
within the given subclass. These characteristics shall include, but need 
not be limited to, aftertreatment device(s), fuel aspiration, air 
injection, exhaust gas recirculation, and feedback type.
    (4) Within the applicable subclass, the five highest selling 
vehicle/engine models that contain the most common such equipment and 
characteristics shall be determined. Any of these five models of the 
current model year (at the time testing begins) may be selected for 
emission generation.
    (i) If one or more of the five models is not available for the 
current model year, the choice of model for emission generation shall be 
limited to those remaining among the five.
    (ii) If fewer than five models of the given vehicle/engine type are 
available for the current model year, all such models shall be eligible.
    (5) When the fuel or fuel additive undergoing testing is not 
commonly used or intended to be used in the vehicle/engine types 
prescribed by this selection procedure, or when rebuilding or alteration 
is required to obtain a suitable vehicle/engine for emission generation, 
the manufacturer may submit a request to EPA for a modification in test 
procedure requirements. Any such request must include objective test 
results which support the claim that a more appropriate vehicle/engine 
type is needed as well as a suggested substitute vehicle/engine type. 
The vehicle/engine selection in this case shall be approved by EPA prior 
to the start of testing.
    (6) Once a particular model has been chosen on which to test a fuel 
or additive product, all mileage accumulation and generation of 
emissions for characterization and biological testing of such product 
shall be conducted on that same model.
    (i) If the initial test vehicle/engine fails or must be replaced for 
any reason, emission generation shall continue with a second vehicle/
engine which is identical to, or resembles to the greatest extent 
possible, the initial test vehicle/engine. If more than one replacement 
vehicle/engine is necessary, all such vehicles/engines shall be 
identical, or resemble to the greatest extent possible, the initial test 
vehicle/engine.
    (ii) Manufacturers are encouraged to obtain, at the start of a test 
program,

[[Page 519]]

more than one emission generation vehicle/engine of the identical model, 
to ensure the availability of back-up emission generator(s). All backup 
vehicles/engines must be conditioned and must have their emissions fully 
characterized, as done for the initial test vehicle/engine, prior to 
their use as emission generators for biological testing. Alternating 
between such vehicles/engines regularly during the course of testing is 
permissible and advisable, particularly to allow regular maintenance on 
such vehicles/engines during prolonged health effects testing.
    (b) Vehicle/engine operation and maintenance. (1) For the purpose of 
generating combustion emissions from a fuel or additive/base fuel 
mixture for which the relevant class is light duty, either a light-duty 
vehicle shall be operated on a chassis dynamometer or a light-duty 
engine shall be operated on an engine dynamometer. When the relevant 
class is heavy duty, the emissions shall be generated on a heavy-duty 
engine operated on an engine dynamometer. In both cases, the vehicle or 
engine model shall be selected as described in paragraph (a) of this 
section and shall have all applicable fuel and emission control systems 
intact.
    (2) Except as provided in Sec. 79.51(h)(2)(iii), the fuel or 
additive/base fuel mixture being tested shall be used at all times 
during operation of the test vehicle or engine. No other fuels or 
additives shall be used in the test vehicle or engine once mileage 
accumulation has begun until emission generation for emission 
characterization and biological testing purposes is completed.
    (i) A vehicle or engine may be used to generate emissions for the 
testing of more than one fuel or additive, provided that all such fuels 
and additives belong to the same fuel family pursuant to 
Sec. 79.56(e)(i), and that, once a vehicle or engine has been used to 
generate emissions for an atypical fuel or additive (pursuant to 
Sec. 79.56(e)(2)(iii)), it shall not be used in the testing of any other 
fuel or additive. Paragraphs (a) (2) and (3) of this section shall apply 
only to the first fuel or additive tested.
    (ii) Prior to being used to generate emissions for testing an 
additional fuel or additive, a vehicle or engine which has previously 
been used for testing a different fuel or additive shall undergo an 
effective intermediate preconditioning cycle to remove the previously 
used fuel and its emissions from the vehicle's fuel and exhaust systems 
and from the combustion emission and evaporative emission control 
systems, if any.
    (iii) Such preconditioning shall include, at a minimum, the 
following steps:
    (A) The canister (if any) shall be removed from the vehicle and 
purged with 300  deg.F nitrogen at 20 liters per minute until the 
incremental weight loss of the canister is less than 1 gram in 30 
minutes. This typically takes 3-4 hours and removes 100 to 120 grams of 
adsorbed gasoline vapors.
    (B) The fuel tank shall be drained and filled to capacity with the 
new test fuel or additive/fuel mixture.
    (C) The vehicle or engine shall be operated until at least 95% of 
the fuel tank capacity is consumed.
    (D) The purged canister shall be returned to the vehicle.
    (E) The fuel tank shall be drained and filled to 40% capacity with 
test fuel.
    (F) Two-hour fuel tank heat builds from 72-120  deg.F shall be 
performed repeatedly as necessary to achieve canister breakthrough. The 
fuel tank must be drained and filled prior to each heat build.
    (3) Scheduled and unscheduled vehicle/engine maintenance. (i) During 
emission generation, vehicles and engines must be maintained in good 
condition by following the recommendations of the original equipment 
manufacturer (OEM) for scheduled service and parts replacement, with 
repairs performed only as necessary. Modifications, adjustments, and 
maintenance procedures contrary to procedures found in 40 CFR part 86 
for the maintenance of test vehicles/engines or performed solely for the 
purpose of emissions improvement are not allowed.
    (ii) If unscheduled maintenance becomes necessary, the vehicle or 
engine must be repaired to OEM specifications, using OEM or OEM-approved 
parts. In addition, the tester is required to measure the basic 
emissions

[[Page 520]]

pursuant to Sec. 79.52(b)(2)(i) after the unscheduled maintenance and 
before resuming testing to ensure that the post-maintenance emissions 
shall be within 20 percent of pre-maintenance emissions levels. If the 
basic emissions cannot be brought within 20 percent of their previous 
levels, then the manufacturer shall restart the emissions 
characterization and health testing of its products combustion emissions 
using a new vehicle/engine.
    (c) Mileage accumulation. (1) A vehicle/engine break-in period is 
required prior to generating emissions for characterization and/or 
biological testing under this subpart. The required mileage accumulation 
may be accomplished on a test track, on the street, on a dynamometer, or 
using any other conventionally accepted method.
    (2) Vehicles to be used in the evaluation of baseline and non-
baseline fuels and fuel additives shall accumulate 4,000 miles prior to 
emission testing. Engines to be used in the evaluation of baseline and 
non-baseline fuels and fuel additives shall accumulate 125 hours of 
operation on an engine dynamometer prior to emission testing.
    (3) When the test formulation is classified as an atypical fuel or 
fuel additive formulation (pursuant to definitions in 
Sec. 79.56(e)(4)(iii)), the following additional mileage accumulation 
requirements apply:
    (i) The test vehicle/engine must be operated for a minimum of 4,000 
vehicle miles or 125 hours of engine operation.
    (ii) Thereafter, at intervals determined by the tester, all emission 
fractions (i.e., vapor, semi-volatile, and particulate) shall be sampled 
and analyzed for the presence and amount of the atypical element(s) and/
or other atypical constituents. Pursuant to paragraph (d) of this 
section, the sampled emissions must be generated in the absence of an 
intact aftertreatment device. Immediately before the samples are taken, 
a brief warmup period (at least ten miles or the engine equivalent) is 
required.
    (iii) Mileage accumulation shall continue until either 50 percent or 
more of the mass of each atypical element (or other atypical 
constituent) entering the engine can be measured in the exhaust 
emissions (all fractions combined), or the vehicle/engine has 
accumulated mileage (or hours) equivalent to 40 percent of the average 
useful life of the applicable vehicle/engine class (pursuant to 
regulations in 40 CFR part 86). For example, the maximum mileage 
required for light-duty vehicles is 40 percent of 100,000 miles (i.e., 
40,000 miles), while the maximum time of operation for heavy-duty 
engines is the equivalent of 40 percent of 290,000 miles (i.e., the 
equivalent in engine hours of 116,000 miles).
    (iv) When either condition in paragraph (c)(3)(iii) of this section 
has been reached, additional emission characterization and biological 
testing of the emissions may begin.
    (d) Use of exhaust aftertreatment devices. (1) If the selected test 
vehicle/engine, as certified by EPA, does not come equipped with an 
emissions aftertreatment device (such as a catalyst or particulate 
trap), such device shall not be used in the context of this program.
    (2) Except as provided in paragraph (d)(3) of this section for 
certain specialized additives, the following provisions apply when the 
test vehicle/engine, as certified by EPA, comes equipped with an 
emissions aftertreatment device.
    (i) For mileage accumulation:
    (A) When the test formulation does not contain any atypical elements 
(pursuant to definitions in Sec. 79.56(e)(4)(iii)), an intact 
aftertreatment device must be used during mileage accumulation.
    (B) When the test formulation does contain atypical elements, then 
the manufacturer may choose to accumulate the required mileage using a 
vehicle/engine equipped with either an intact aftertreatment device or 
with a non-functional aftertreatment device (e.g., a blank catalyst 
without its catalytic wash coat). In either case, sampling and analysis 
of emissions for measurement of the mass of the atypical element(s) (as 
described in Sec. 79.57(c)(3)) must be done on emissions generated with 
a non-functional (blank) aftertreatment device.
    (1) If the manufacturer chooses to accumulate mileage without a 
functional aftertreatment device, and if the manufacturer wishes to do 
this outside of a laboratory/test track setting, then a

[[Page 521]]

memorandum of exemption for product testing must be obtained by applying 
to the Director of the Field Operations and Support Division (see 
Sec. 79.59(a)(1)).
    (2) [Reserved]
    (ii) For Tier 1 (Sec. 79.52), the total set of requirements for the 
characterization of combustion emissions (Sec. 79.52(b)) must be 
completed two times, once using emissions generated with the 
aftertreatment device intact and a second time with the aftertreatment 
device rendered nonfunctional or replaced with a non-functional 
aftertreatment device as described in paragraph (d)(2)(i)(B) of this 
section.
    (iii) For Tier 2 (Sec. 79.53), the standard requirements for 
biological testing of combustion emissions shall be conducted using 
emissions generated with a non-functioning aftertreatment device as 
described in paragraph (d)(2)(i)(B) of this section.
    (iv) For alternative Tier 2 requirements (Sec. 79.58(c)) or Tier 3 
requirements (Sec. 79.54) which may be prescribed by EPA, the use of 
functional or nonfunctional aftertreatment devices shall be specified by 
EPA as part of the test guidelines.
    (v) In the case where an intact aftertreatment device is not in 
place, all other manufacturer-specified combustion characteristics 
(e.g., back pressure, residence time, and mixing characteristics) of the 
altered vehicle/engine shall be retained to the greatest extent 
possible.
    (3) Notwithstanding paragraphs (d)(1) and (d)(2) of this section, 
when the subject of testing is a fuel additive specifically intended to 
enhance the effectiveness of exhaust aftertreatment devices, the related 
aftertreatment device may be used on the emission generation vehicle/
engine during all mileage accumulation and testing.
    (e) Generation of combustion emissions--(1) Generating combustion 
emissions for emission characterization. (i) Combustion emissions shall 
be generated according to the exhaust emission portion of the Federal 
Test Procedure (FTP) for the certification of new motor vehicles, found 
in 40 CFR part 86, subpart B for light-duty vehicles/engines, and 
subparts D, M and N for heavy-duty vehicles/engines. The Urban 
Dynamometer Driving Schedule (UDDS), pursuant to 40 CFR part 86, 
appendix I(a), shall apply to light-duty vehicles/engines and the Engine 
Dynamometer Driving Schedule (EDS), pursuant to 40 CFR part 86, appendix 
I(f)(2), shall apply to heavy-duty vehicles/engines. The motoring 
portion of the heavy-duty test cycle may be eliminated, at the 
manufacturer's option, for the generation of emissions.
    (A) For light-duty engines operated on an engine dynamometer, the 
tester shall determine the speed-torque equivalencies (``trace'') for 
its test engine from valid FTP testing performed on a chassis 
dynamometer, using a test vehicle with an engine identical to that being 
tested. The test engine must then be operated under these speed and 
torque specifications to simulate the FTP cycle.
    (B) Special procedures not included in the FTP may be necessary in 
order to characterize emissions from fuels and fuel additives containing 
atypical elements or to collect some types of emissions (e.g., 
particulate emissions from light-duty vehicles/engines, semi-volatile 
emissions from both light-duty and heavy-duty vehicles/engines). Such 
alterations to the FTP are acceptable.
    (C) For Tier 2 testing, the engines shall operate on repeated bags 2 
and 3 of the UDDS or back to back repeats of the heavy-duty transient 
cycle of the EDS.
    (ii) Pursuant to Sec. 79.52(b)(1)(i) and Sec. 79.57(d)(2)(ii), 
emission generation and characterization must be repeated three times 
when the selected vehicle/engine is normally operated without an 
emissions aftertreatment device and six times when the selected vehicle/
engine is normally operated with an emissions aftertreatment device. In 
the latter case, the emission generation and characterization process 
shall be repeated three times with the intact aftertreatment device in 
place and three times with a non-functioning (blank) aftertreatment 
device in place.
    (iii) From both light-duty and heavy-duty vehicles/engines, samples 
of vapor phase, semi-volatile phase, and particulate phase emissions 
shall be collected, except that semi-volatile phase, and particulate 
emissions need not be sampled for fuels and additives in the

[[Page 522]]

methane and propane families (pursuant to Sec. 79.56(e)(1)(v) and (vi)). 
The number and type of samples to be collected and separately analyzed 
during one emission generation/characterization process are as follows:
    (A) In the case of combustion emissions generated from light-duty 
vehicles/engines, the samples consist of three bags of vapor emissions 
(one from each segment of the light-duty exhaust emission cycle) plus 
one sample of particulate-phase emissions and one sample of semi-
volatile-phase emissions (collected over all segments of the exhaust 
emission cycle). If the mass of particulate emissions or semi-volatile 
emissions obtained during one driving cycle is not sufficient for 
characterization, up to three driving cycles may be performed and the 
extracted fractions combined prior to chemical analysis. Particulate-
phase emissions shall not be combined with semi-volatile-phase 
emissions. The test laboratory should focus on the characterization of 
the limit of detection for particulates and semi-volatile emissions.
    (B) In the case of combustion emissions generated from heavy-duty 
engines, the samples consist of one sample of each emission phase 
(vapor, particulate, and semi-volatile) collected over the entire cold-
start cycle and a second sample of each such phase collected over the 
entire hot-start cycle (see 40 CFR 86.334 through 86.342).
    (iv) Emission collection and storage. (A) Vapor phase emissions 
shall be collected and stored in Tedlar bags for subsequent chemical 
analysis. Storage conditions are specified in Sec. 79.52(b)(2).
    (B) Particulate phase emissions shall be collected on a particulate 
filter (or more than one, if required) using methods described in 40 CFR 
86.1301 through 86.1344. These methods, ordinarily applied only to 
heavy-duty emissions, are to be adapted and used for collection of 
particulates from light-duty vehicles/engines, as well. The particulate 
matter may be stored on the filter in a sealed container, or the soluble 
organic fraction may be extracted and stored in a separate sealed 
container. Both the particulate and the extract shall be shielded from 
ultraviolet light and stored at -20  deg.C or less. Particulate 
emissions shall be tested no later than six months from the date they 
were generated.
    (C) Semi-volatile emissions shall be collected immediately 
downstream from the particulate collection filters using porous polymer 
resin beds, or their equivalent, designed for their capture. The soluble 
organic fraction of semi-volatile emissions shall be extracted 
immediately and tested within six months of being generated. The extract 
shall be stored in a sealed container which is shielded from ultraviolet 
light and stored at -20  deg.C or less.
    (D) Particulate and semi-volatile phase emission collection, 
handling and extraction methods shall not alter the composition of the 
collected material, to the extent possible.
    (v) Additional requirements for combustion emission sampling, 
storage, and characterization are specified in Sec. 79.52(b).
    (2) Generating whole combustion emissions for biological testing. 
(i) Biological tests requiring whole combustion emissions shall be 
conducted using emissions generated from the test vehicle or engine 
operated in accordance with general FTP requirements.
    (ii) Light-duty test vehicles/engines shall be repeatedly operated 
over the Urban Dynamometer Driving Schedule (UDDS) (or equivalent engine 
dynamometer trace, per paragraph (e)(1)(i)(A) of this section) and 
heavy-duty test engines shall be repeatedly operated over the Engine 
Dynamometer Schedule (EDS) (see 40 CFR part 86, appendix I).
    (A) The tolerances of the driving cycle shall be two times those of 
the Federal Test Procedure and must be met 95 percent of the time.
    (B) The UDDS or EDS shall be repeated as many times as required for 
the biological test session.
    (C) Light-duty dynamometers shall be calibrated prior to the start 
of a biological test (40 CFR 86.118-78), verified weekly (40 CFR 86.118-
78), and recalibrated as required. Heavy-duty dynamometers shall be 
calibrated and checked prior to the start of a biological test (40 CFR 
86.1318-84), recalibrated every two weeks (40 CFR 86.1318-84(a)) and 
checked as stated in 40 CFR 86.1318-84(b) and (c).

[[Page 523]]

    (D) The fuel reservoir for the test vehicle/engine shall be large 
enough to operate the test vehicle/engine throughout the daily 
biological exposure period, avoiding the need for refueling during 
testing.
    (iii) An apparatus to integrate the large concentration swings 
typical of transient-cycle exhaust is to be used between the source of 
emissions and the exposure chamber containing the animal test cages(s). 
The purpose of such apparatus is to decrease the variability of the 
biological exposure atmosphere and achieve the necessary concentration 
of CO or NOX, whichever is limiting.
    (A) A large mixing chamber is suggested for this purpose. The mixing 
chamber would be charged from the CVS at a constant rate determined by 
the exposure chamber purge rate. Flow to the exposure chamber would 
begin at the conclusion of the initial transient cycle with the 
associated mixing chamber charge.
    (B) A potential alternative apparatus is a mini-diluter (see, for 
example, AIGER/CRADA, February, 1994 in Sec. 79.57(g)).
    (C) [Reserved]
    (iv) Emission dilution. (A) Dilution air can be pre-dried to lower 
the relative humidity, thus permitting a lower dilution rate and a 
higher concentration of hydrocarbons to be achieved without condensation 
of water vapor.
    (B) These procedures include requirements that the mean exposure 
concentration in the inhalation test chamber on 90 percent or more of 
the exposure days shall be controlled as follows:
    (1) If the species being controlled is hydrocarbon or particulate, 
the mean exposure concentration must be within 15 percent of the target 
concentration for the single species being controlled.
    (2) For other species, the mean exposure concentration must be 
within 10 percent of the target concentration for the single species 
being controlled.
    (3) For all species, daily monitoring of CO, CO2, 
NOX, SOX, and total hydrocarbons in the exposure 
chamber shall be required. Analysis of the particle size distribution 
shall also be performed to establish the stability and consistency of 
particle size distribution in the test exposure.
    (C) After the initial exhaust dilution to preserve the character of 
the exhaust, the exhaust stream can be further diluted in the mixing 
chamber (and/or after leaving the chamber) to achieve the desired 
biological exposure concentrations.
    (v) Verification procedures. (A) The entire system used to dilute 
and transport whole combustion emissions (i.e., from exhaust pipe to 
outlet in the biological testing chamber) shall be verified before any 
animal exposures begin, and verified at least weekly during testing. 
(See procedures at 40 CFR 86.119-90 for light-duty vehicles and 
Sec. 86.1319-90 for heavy-duty engines.) Verification testing shall be 
accomplished by introducing a known sample at the end of the vehicle/
engine exhaust pipe into the dilution system and measuring the amount 
exiting the system. For example, an injected hydrocarbon sample could be 
detected with a gas chromatograph (GC) and flame ionization detector 
(FID) to determine the recovery factor.
    (B) [Reserved]
    (vi) Emission exposure quality control. (A) The tester shall 
incorporate the additional quality assurance and safety procedures 
outlined in Sec. 79.61(d) to control variability of emissions during the 
generation of exposure emissions during health effect testing.
    (B) These procedures include requirements that the mean exposure 
concentration in the inhalation test chamber on 90 percent or more of 
the exposure days shall be controlled as follows:
    (1) If the species being controlled is hydrocarbon or particulate, 
the mean exposure concentration must be within 15 percent of the target 
concentration for the single species being controlled.
    (2) For other species, the mean exposure concentration must be 
within 10 percent of the target concentration for the single species 
being controlled.
    (3) For all species, daily monitoring of CO, CO2, 
NOX, SOX, and total hydrocarbons in the exposure 
chamber shall be required. Analysis of the particle size distribution 
shall also be performed to establish the stability and consistency of 
particle size distribution in the test exposure.

[[Page 524]]

    (C) The testing facility shall allow an audit of its premises, the 
qualifications, e.g., curriculum vitae, of its staff assigned to 
testing, and the specimens and records of the testing for registration 
purposes (as specified in Sec. 79.60).
    (vii) To allow for customary laboratory scheduling and unforeseen 
problems affecting the combustion emission generation or dilution 
equipment, biological exposures may be interrupted on limited occasions, 
as specified in Sec. 79.61(d)(5). Interruptions exceeding these 
limitations shall cause the affected test(s) to be void. Testers shall 
be aware of concerns for backup vehicles/engines cited in paragraph 
(a)(7)(ii) of this section.
    (3) Generating particulate and semi-volatile emissions for 
biological testing. (i) Salmonella mutagenicity testing, pursuant to 
Sec. 79.68, shall be conducted on extracts of the particulate and semi-
volatile emission phases separately. These emissions shall be generated 
by operating the test vehicle/engine over the appropriate FTP driving 
schedule (see paragraph (e)(2)(ii) of this section) and collected and 
analyzed according to methods described in 40 CFR 86.1301 through 1344 
(further information on this subject may be found in Perez, et al. CRC 
Report No. 551, 1987 listed in Sec. 79.57(g)).
    (A) Particulate emissions shall be collected on particulate filters 
and extracted from the collection equipment for use in biological tests. 
The number of repetitions of the applicable driving schedule required to 
collect sufficient quantities of the particulate emissions will vary, 
depending on the characteristics of the engine, the test fuel, and the 
requirements of the biological test protocol. The particulate sample may 
be collected on one or more filters, as necessary.
    (B) Semi-volatile emissions shall be collected immediately 
downstream from the particulate collection filters using porous polymer 
resin beds, or their equivalent, designed for their capture. Semi-
volatile phase emissions shall be collected on one apparatus. The time 
spent collecting sufficient quantities of the test substances in 
emissions samples will vary, depending on the emission characteristics 
of the engine and fuel or additive/base fuel mixture and on the 
requirements of the biological test protocol.
    (ii) The extraction method shall be determined by the specifications 
of the biological test for which the emissions are used.
    (iii) Particulate and semi-volatile emission storage requirements 
are as specified in Sec. 79.57(e)(1)(iv).
    (iv) Particulate and semi-volatile phase emission collection, 
handling and extraction methods shall not alter the composition of the 
collected material, to the extent possible.
    (v) Particulate emissions shall not be combined with semi-volatile 
phase emissions.
    (f) Generation of evaporative emissions for characterization and 
biological testing. (1) Except as provided in paragraph (f)(5) of this 
section, an evaporative emissions generator shall be used to volatilize 
samples of a fuel or additive/base fuel mixture for evaporative 
emissions characterization and biological testing. Emissions shall be 
collected and sampled using equipment and methods appropriate for use 
with the compounds being characterized and the requirements of the 
emission characterization analysis. In the case of potentially explosive 
test substance concentrations, care must be taken to avoid generating 
explosive atmospheres. The tester is referred to Sec. 79.61(d)(8) for 
considerations involving explosivity.
    (2) Evaporative Emissions Generator (EEG) Description. An EEG is a 
fuel tank or vessel to which heat is applied causing a portion of the 
fuel to evaporate at a desired rate. The manufacturer has flexibility in 
designing an EEG for testing a particular fuel or fuel additive. The 
sample used to generate emissions in the EEG shall be renewed at least 
daily.
    (i) The evaporation chamber shall be made from materials compatible 
with the fuels and additives being tested and shall be equipped with a 
drain.
    (ii) The chamber shall be filled to 40 5 percent of its 
interior volume with the fuel or additive/base fuel mixture being 
tested, with the remainder of the volume containing air.
    (iii) The concentration of the evaporated fuel or additive/base fuel 
mixture in the vapor space of the evaporation

[[Page 525]]

chamber during the time emissions are being withdrawn for testing shall 
not vary by more than 10 percent from the equilibrium concentration in 
the vapor space of emissions generated from the fresh fuel or additive/
base fuel mixture in the chamber.
    (A) During the course of a day's emission generation period, the 
level of fuel in the EEG shall be maintained to within 7 percent of its 
height at the start of the daily exposure period.
    (B) The fuel used in the EEG shall be drained at the end of each 
daily exposure. The EEG shall be refilled with a fresh supply of the 
test formulation before the start of each daily exposure.
    (C) The vapor space of the evaporation chamber shall be well mixed 
throughout the time emissions are being withdrawn for testing.
    (iv) The size of the evaporation chamber shall be determined by the 
rate at which evaporative emissions shall be needed in the test animal 
exposure chambers and the rate at which the fuel or the additive/base 
fuel mixture evaporates. The rate of evaporative emissions may be 
adjusted by altering the size of the EEG or by using one or more 
additional EEG(s). Emission rate modifications shall not be adjusted by 
temperature control or pressure control.
    (v) The temperature of the fuel or additive/base fuel mixture in the 
evaporation chamber shall be 130  deg.F5  deg.F. The vapors 
shall maintain this temperature up to the point in the system where the 
vapors are diluted.
    (vi) The pressure in the vapor space of the evaporation chamber and 
the dilution and sampling apparatus shall stay within 10 percent of 
ambient atmospheric pressure.
    (vii) There shall be no controls or equipment on the evaporation 
chamber system that change the concentration or composition of the 
vapors generated for testing.
    (viii) Manufacturers shall perform verification testing of 
evaporative emissions in a manner analogous to the verification testing 
performed for combustion emissions.
    (3) For biological testing, vapor shall be withdrawn from the EEG at 
a constant rate, diluted with air as required for the particular study, 
and conducted immediately to the biological testing chamber(s) in a 
manner similar to the method used in Sec. 79.57(e), excluding the mixing 
chamber therein. The rate of emission generation shall be high enough to 
supply the biological exposure chamber with sufficient emissions to 
allow for a minimum of fifteen air changes per exposure chamber per 
hour. To allow for customary laboratory scheduling and for unforeseen 
problems with the evaporative emission generation or dilution equipment, 
biological exposures may be interrupted on limited occasions, as 
specified in Sec. 79.61(d)(5). Interruptions exceeding these limitations 
shall cause the affected test(s) to be void.
    (4) For characterization of evaporative emissions, samples of 
equilibrated emissions to the vapor space of the EEG shall be withdrawn 
into Tedlar bags, then stored and analyzed as specified in 
Sec. 79.52(b).
    (5) A manufacturer (or group of manufacturers) may submit to EPA a 
request for approval of an alternative method of generating evaporative 
emissions for use in emission characterization and biological tests 
required under this subpart.
    (i) To be approved by EPA, the request must fully explain the 
rationale for the proposed method as well as the technical procedures, 
quality control, and safety precautions to be used, and must demonstrate 
that the proposed method will meet the following criteria:
    (A) The emission mixture generated by the proposed procedures must 
be reasonably similar to the equilibrium composition of the vapor which 
occurs in the vehicle fuel tank head space when the subject fuel or 
additive/base fuel mixture is in use and near-maximum in-use 
temperatures are encountered.
    (B) The emissions mixture generated by the proposed method must be 
sufficiently concentrated to provide adequate exposure levels in the 
context of the required toxicologic tests.
    (C) The proposed method must include procedures to ensure that the 
emissions delivered to the biologic exposure chambers will provide a 
reasonably constant exposure atmosphere over time.

[[Page 526]]

    (ii) If EPA approves the request, EPA will place in the public 
record a copy of the request, together with all supporting procedural 
descriptions and justifications, and will notify the public of its 
availability by publishing a notice in the Federal Register.
    (g) References. For additional background information on the 
emission generation procedures outlined in this paragraph (g), the 
following references may be consulted. Additional references can be 
found in Sec. 79.61(f).
    (1) AIGER/CRADA (American Industry/Government Emissions Research 
Cooperative Research and Development Agreement, ``Specifications for 
Advanced Emissions Test Instrumentation'' AIGER PD-94-1, Revision 5.0, 
February, 1994
    (2) Black, F. and R. Snow, ``Constant Volume Sampling System Water 
Condensation'' SAE 940970 in ``Testing and Instrumentation'' 
SP-1039, Society of Automotive Engineers, Feb. 28-Mar. 3, 1994.
    (3) Perez, J.M., Jass, R.E., Leddy, D.G., eds. ``Chemical Methods 
for the Measurement of Unregulated Diesel Emissions (CRC-APRAC Project 
No. CAPI-1-64), Coordinating Research Council, CRC Report No. 551, 
August, 1987.
    (4) Phalen, R.F., ``Inhalation Studies: Foundations and 
Techniques'', CRC Press, Inc., Boca Raton, Florida, 1984.

[59 FR 33093, June 27, 1994, as amended at 61 FR 36511, July 11, 1996; 
63 FR 63792, Nov. 17, 1998]