[Code of Federal Regulations]
[Title 49, Volume 2]
[Revised as of October 1, 2004]
From the U.S. Government Printing Office via GPO Access
[CITE: 49CFR172.102]
[Page 316-345]
TITLE 49--TRANSPORTATION
CHAPTER I--RESEARCH AND SPECIAL PROGRAMS ADMINISTRATION, DEPARTMENT OF
TRANSPORTATION
PART 172_HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS
Subpart B_Table of Hazardous Materials and Special Provisions
Sec. 172.102 Special provisions.
(a) General. When column 7 of the Sec. 172.101 table refers to a
special provision for a hazardous material, the meaning and requirements
of that provision are as set forth in this section. When a special
provision specifies packaging or packaging requirements--
(1) The special provision is in addition to the standard
requirements for all packagings prescribed in Sec. 173.24 of this
subchapter and any other applicable packaging requirements in subparts A
and B of part 173 of this subchapter; and
[[Page 317]]
(2) To the extent a special provision imposes limitations or
additional requirements on the packaging provisions set forth in column
8 of the Sec. 172.101 table, packagings must conform to the
requirements of the special provision.
(b) Description of codes for special provisions. Special provisions
contain packaging provisions, prohibitions, exceptions from requirements
for particular quantities or forms of materials and requirements or
prohibitions applicable to specific modes of transportation, as follows:
(1) A code consisting only of numbers (for example, ``11'') is
multi-modal in application and may apply to bulk and non-bulk
packagings.
(2) A code containing the letter ``A'' refers to a special provision
which applies only to transportation by aircraft.
(3) A code containing the letter ``B'' refers to a special provision
which applies only to bulk packaging requirements. Unless otherwise
provided in this subchapter, these special provisions do not apply to IM
portable tanks.
(4) A code containing the letter ``H'' refers to a special provision
which applies only to transportation by highway.
(5) A code containing the letter ``N'' refers to a special provision
which applies only to non-bulk packaging requirements.
(6) A code containing the letter ``R'' refers to a special provision
which applies only to transportation by rail.
(7) A code containing the letter ``T'' refers to a special provision
which applies only to transportation in IM portable tanks.
(8) A code containing the letter ``W'' refers to a special provision
which applies only to transportation by water.
(c) Tables of special provisions. The following tables list, and set
forth the requirements of, the special provisions referred to in column
7 of the Sec. 172.101 table.
(1) Numeric provisions. These provisions are multi-modal and apply
to bulk and non-bulk packagings:
Code/Special Provisions
1 This material is poisonous by inhalation (see Sec. 171.8 of this
subchapter) in Hazard Zone A (see Sec. 173.116(a) or Sec. 173.133(a)
of this subchapter), and must be described as an inhalation hazard under
the provisions of this subchapter.
2 This material is poisonous by inhalation (see Sec. 171.8 of this
subchapter) in Hazard Zone B (see Sec. 173.116(a) or Sec. 173.133(a)
of this subchapter), and must be described as an inhalation hazard under
the provisions of this subchapter.
3 This material is poisonous by inhalation (see Sec. 171.8 of this
subchapter) in Hazard Zone C (see Sec. 173.116(a) of this subchapter),
and must be described as an inhalation hazard under the provisions of
this subchapter.
4 This material is poisonous by inhalation (see Sec. 171.8 of this
subchapter) in Hazard Zone D (see Sec. 173.116(a) of this subchapter),
and must be described as an inhalation hazard under the provisions of
this subchapter.
5 If this material meets the definition for a material poisonous by
inhalation (see Sec. 171.8 of this subchapter), a shipping name must be
selected which identifies the inhalation hazard, in Division 2.3 or
Division 6.1, as appropriate.
6 This material is poisonous-by-inhalation and must be described as an
inhalation hazard under the provisions of this subchapter.
8 A hazardous substance that is not a hazardous waste may be shipped
under the shipping description ``Other regulated substances, liquid or
solid, n.o.s.'', as appropriate. In addition, for solid materials,
special provision B54 applies.
9 Packaging for certain PCBs for disposal and storage is prescribed by
EPA in 40 CFR 761.60 and 761.65.
11 The hazardous material must be packaged as either a liquid or a
solid, as appropriate, depending on its physical form at 55 [deg]C (131
[deg]F) at atmospheric pressure.
12 In concentrations greater than 40 percent, this material has strong
oxidizing properties and is capable of starting fires in contact with
combustible materials. If appropriate, a package containing this
material must conform to the additional labeling requirements of Sec.
172.402 of this subchapter.
13 The words ``Inhalation Hazard'' shall be entered on each shipping
paper in association with the shipping description, shall be marked on
each non-bulk package in association with the proper shipping name and
identification number, and shall be marked on two opposing sides of each
bulk package. Size of marking on bulk package must conform to Sec.
172.302(b) of this subchapter. The requirements of Sec. Sec. 172.203(m)
and 172.505 of this subchapter do not apply.
14 Motor fuel antiknock mixtures are:
a. Mixtures of one or more organic lead mixtures (such as tetraethyl
lead,
[[Page 318]]
triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and
tetramethyl lead) with one or more halogen compounds (such as ethylene
dibromide and ethylene dichloride), hydrocarbon solvents or other
equally efficient stabilizers; or
b. tetraethyl lead.
15 This entry applies to ``Chemical kits'' and ``First aid kits''
containing one or more compatible items of hazardous materials in boxes,
cases, etc. that are used for medical, analytical, diagnostic or testing
purposes. For transportation by aircraft, materials forbidden for
transportation by passenger aircraft or cargo aircraft may not be
included in the kits. Chemical kits and first aid kits are excepted from
the specification packaging requirements of this subchapter when
packaged in combination packagings. Chemical kits and first aid kits are
also excepted from the labeling and placarding requirements of this
subchapter, except when offered for transportation or transported by
air. Chemical and first aid kits may be transported in accordance with
the consumer commodity and ORM exceptions in Sec. 173.156, provided
they meet all required conditions. Kits that are carried on board
transport vehicles for first aid or operating purposes are not subject
to the requirements of this subchapter.
16 This description applies to smokeless powder and other solid
propellants that are used as powder for small arms and have been classed
as Division 1.3 and 4.1 in accordance with Sec. 173.56 of this
subchapter.
18 This description is authorized only for fire extinguishers listed in
Sec. 173.309(b) of this subchapter meeting the following conditions:
a. Each fire extinguisher may only have extinguishing contents that
are nonflammable, non-poisonous, non-corrosive and commercially free
from corroding components.
b. Each fire extinguisher must be charged with a nonflammable, non-
poisonous, dry gas that has a dew-point at or below minus 46.7 [deg]C
(minus 52 [deg]F) at 101 kPa (1 atmosphere) and is free of corroding
components, to not more than the service pressure of the cylinder.
c. A fire extinguisher may not contain more than 30% carbon dioxide
by volume or any other corrosive extinguishing agent.
d. Each fire extinguisher must be protected externally by suitable
corrosion-resisting coating.
19 For domestic transportation only, the identification number
``UN1075'' may be used in place of the identification number specified
in column (4) of the Sec. 172.101 table. The identification number used
must be consistent on package markings, shipping papers and emergency
response information.
21 This material must be stabilized by appropriate means (e.g., addition
of chemical inhibitor, purging to remove oxygen) to prevent dangerous
polymerization (see Sec. 173.21(f) of this subchapter).
22 If the hazardous material is in dispersion in organic liquid, the
organic liquid must have a flash point above 50 [deg]C (122 [deg]F).
23 This material may be transported under the provisions of Division 4.1
only if it is so packed that the percentage of diluent will not fall
below that stated in the shipping description at any time during
transport. Quantities of not more than 500 g per package with not less
than 10 percent water by mass may also be classed in Division 4.1,
provided a negative test result is obtained when tested in accordance
with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see
Sec. 171.7 of this subchapter).
24 Alcoholic beverages containing more than 70 percent alcohol by volume
must be transported as materials in Packing Group II. Alcoholic
beverages containing more than 24 percent but not more than 70 percent
alcohol by volume must be transported as materials in Packing Group III.
26 This entry does not include ammonium permanganate, the transport of
which is prohibited except when approved by the Associate Administrator.
28 The dihydrated sodium salt of dichloroisocyanuric acid is not subject
to the requirements of this subchapter.
29 Lithium cells and batteries and equipment containing or packed with
lithium cells and batteries which do not comply with the provisions of
Sec. 173.185 of this subchapter may be transported only if they are
approved by the Associate Administrator.
30 Sulfur is not subject to the requirements of this subchapter if
transported in a non-bulk packaging or if formed to a specific shape
(for example, prills, granules, pellets, pastilles, or flakes). A bulk
packaging containing sulfur is not subject to the placarding
requirements of subpart F of this part, if it is marked with the
appropriate identification number as required by subpart D of this part.
Molten sulfur must be marked as required by Sec. 172.325 of this
subchapter.
31 Materials which have undergone sufficient heat treatment to render
them non-hazardous are not subject to the requirements of this
subchapter.
32 Polymeric beads and molding compounds may be made from polystyrene,
poly(methyl methacrylate) or other polymeric material.
33 Ammonium nitrites and mixtures of an inorganic nitrite with an
ammonium salt are prohibited.
[[Page 319]]
34 The commercial grade of calcium nitrate fertilizer, when consisting
mainly of a double salt (calcium nitrate and ammonium nitrate)
containing not more than 10 percent ammonium nitrate and at least 12
percent water of crystallization, is not subject to the requirements of
this subchapter.
35 Antimony sulphides and oxides which do not contain more than 0.5
percent of arsenic calculated on the total mass do not meet the
definition of Division 6.1.
36 The maximum net quantity per package is 5 L (1 gallon) or 5 kg (11
pounds).
37 Unless it can be demonstrated by testing that the sensitivity of the
substance in its frozen state is no greater than in its liquid state,
the substance must remain liquid during normal transport conditions. It
must not freeze at temperatures above -15 [deg]C (5 [deg]F).
38 If this material shows a violent effect in laboratory tests involving
heating under confinement, the labeling requirements of Special
Provision 53 apply, and the material must be packaged in accordance with
packing method OP6 in Sec. 173.225 of this subchapter. If the SADT of
the technically pure substance is higher than 75 [deg]C, the technically
pure substance and formulations derived from it are not self-reactive
materials and, if not meeting any other hazard class, are not subject to
the requirements of this subchapter.
39 This substance may be carried under provisions other than those of
Class 1 only if it is so packed that the percentage of water will not
fall below that stated at any time during transport. When phlegmatized
with water and inorganic inert material, the content of urea nitrate
must not exceed 75 percent by mass and the mixture should not be capable
of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of
Tests and Criteria (IBR, see Sec. 171.7 of this subchapter).
40 Polyester resin kits consist of two components: a base material
(Class 3, Packing Group II or III) and an activator (organic peroxide),
each separately packed in an inner packaging. The organic peroxide must
be type D, E, or F, not requiring temperature control, and be limited to
a quantity of 125 mL (4.22 ounces) per inner packaging if liquid, and
500 g (1 pound) if solid. The components may be placed in the same outer
packaging provided they will not interact dangerously in the event of
leakage. Packing group will be II or III, according to the criteria for
Class 3, applied to the base material.
43 The membrane filters, including paper separators and coating or
backing materials, that are present in transport, must not be able to
propagate a detonation as tested by one of the tests described in the UN
Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see Sec.
171.7 of this subchapter). On the basis of the results of suitable
burning rate tests, and taking into account the standard tests in the UN
Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see
Sec. 171.7 of this subchapter), nitrocellulose membrane filters in the
form in which they are to be transported that do not meet the criteria
for a Division 4.1 material are not subject to the requirements of this
subchapter. Packagings must be so constructed that explosion is not
possible by reason of increased internal pressure. Nitrocellulose
membrane filters covered by this entry, each with a mass not exceeding
0.5 g, are not subject to the requirements of this subchapter when
contained individually in an article or a sealed packet.
44 The formulation must be prepared so that it remains homogenous and
does not separate during transport. Formulations with low nitrocellulose
contents and neither showing dangerous properties when tested for their
ability to detonate, deflagrate or explode when heated under defined
confinement by the appropriate test methods and criteria in the UN
Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter),
nor classed as a Division 4.1 (flammable solid) when tested in
accordance with the procedures specified in Sec. 173.124 of this
subchapter (chips, if necessary, crushed and sieved to a particle size
of less than 1.25 mm), are not subject to the requirements of this
subchapter.
45 Temperature should be maintained between 18 [deg]C (64.4 [deg]F) and
40 [deg]C (104 [deg]F). Tanks containing solidified methacrylic acid
must not be reheated during transport.
46 This material must be packed in accordance with packing method OP6
(see Sec. 173.225 of this subchapter). During transport, it must be
protected from direct sunshine and stored (or kept) in a cool and well-
ventilated place, away from all sources of heat.
47 Mixtures of solids which are not subject to this subchapter and
flammable liquids may be transported under this entry without first
applying the classification criteria of Division 4.1, provided there is
no free liquid visible at the time the material is loaded or at the time
the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level. Small inner packagings consisting of sealed
packets containing less than 10 mL of a Class 3 liquid in Packing Group
II or III absorbed onto a solid material are not subject to this
subchapter provided there is no free liquid in the packet.
48 Mixtures of solids which are not subject to this subchapter and toxic
liquids may be transported under this entry without first
[[Page 320]]
applying the classification criteria of Division 6.1, provided there is
no free liquid visible at the time the material is loaded or at the time
the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level. This entry may not be used for solids containing
a Packing Group I liquid.
49 Mixtures of solids which are not subject to this subchapter and
corrosive liquids may be transported under this entry without first
applying the classification criteria of Class 8, provided there is no
free liquid visible at the time the material is loaded or at the time
the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level.
50 Cases, cartridge, empty with primer which are made of metallic or
plastic casings and meeting the classification criteria of Division 1.4
are not regulated for domestic transportation.
51 This description applies to items previously described as ``Toy
propellant devices, Class C'' and includes reloadable kits. Model rocket
motors containing 30 grams or less propellant are classed as Division
1.4S and items containing more than 30 grams of propellant but not more
than 62.5 grams of propellant are classed as Division 1.4C.
52 This entry may only be used for substances that do not exhibit
explosive properties of Class 1 (explosive) when tested in accordance
with Test Series 1 and 2 of Class 1 (explosive) in the UN Manual of
Tests and Criteria, Part I (incorporated by reference; see Sec. 171.7
of this subchapter).
53 Packages of these materials must bear the subsidiary risk label,
``EXPLOSIVE'', unless otherwise provided in this subchapter or through
an approval issued by the Associate Administrator, or the competent
authority of the country of origin. A copy of the approval shall
accompany the shipping papers.
54 Maneb or maneb preparations not meeting the definition of Division
4.3 or any other hazard class are not subject to the requirements of
this subchapter when transported by motor vehicle, rail car, or
aircraft.
55 This device must be approved in accordance with Sec. 173.56 of this
subchapter by the Associate Administrator.
56 A means to interrupt and prevent detonation of the detonator from
initiating the detonating cord must be installed between each electric
detonator and the detonating cord ends of the jet perforating guns
before the charged jet perforating guns are offered for transportation.
57 Maneb or Maneb preparations stabilized against self-heating need not
be classified in Division 4.2 when it can be demonstrated by testing
that a volume of 1 m3 of substance does not self-ignite and
that the temperature at the center of the sample does not exceed 200
[deg]C, when the sample is maintained at a temperature of not less than
75 [deg]C 2 [deg]C for a period of 24 hours, in
accordance with procedures set forth for testing self-heating materials
in the UN Manual of Tests and Criteria (IBR, see Sec. 171.7 of this
subchapter).
58 Aqueous solutions of Division 5.1 inorganic solid nitrate substances
are considered as not meeting the criteria of Division 5.1 if the
concentration of the substances in solution at the minimum temperature
encountered in transport is not greater than 80% of the saturation
limit.
59 Ferrocerium, stabilized against corrosion, with a minimum iron
content of 10 percent is not subject to the requirements of this
subchapter.
60 After September 30, 1997, an oxygen generator, chemical, that is
shipped with its means of initiation attached must incorporate at least
two positive means of preventing unintentional actuation of the
generator, and be classed and approved by the Associate Administrator.
The procedures for approval of a chemical oxygen generator that contains
an explosive means of initiation (e.g., a primer or electric match) are
specified in Sec. 173.56 of this subchapter. Each person who offers a
chemical oxygen generator for transportation after September 30, 1997,
shall: (1) ensure that it is offered in conformance with the conditions
of the approval; (2) maintain a copy of the approval at each facility
where the chemical oxygen generator is packaged; and (3) mark the
approval number on the outside of the package.
61 A chemical oxygen generator is spent if its means of ignition and all
or a part of its chemical contents have been expended.
64 The group of alkali metals includes lithium, sodium, potassium,
rubidium, and caesium.
65 The group of alkaline earth metals includes magnesium, calcium,
strontium, and barium.
66 Formulations of these substances containing not less than 30 percent
non-volatile, non-flammable phlegmatizer are not subject to this
subchapter.
70 Black powder that has been classed in accordance with the
requirements of Sec. 173.56 of this subchapter may be reclassed and
offered for domestic transportation as a Division 4.1 material if it is
offered for transportation and transported in accordance with the
limitations and packaging requirements of Sec. 173.170 of this
subchapter.
74 During transport, this material must be protected from direct
sunshine and stored
[[Page 321]]
or kept in a cool and well-ventilated place, away from all sources of
heat.
77 For domestic transportation, a Division 5.1 subsidiary risk label is
required only if a carbon dioxide and oxygen mixture contains more than
23.5% oxygen.
78 This entry may not be used to describe compressed air which contains
more than 23.5 percent oxygen. An oxidizer label is not required for any
oxygen concentration of 23.5 percent or less.
79 This entry may not be used for mixtures that meet the definition for
oxidizing gas.
81 Polychlorinated biphenyl items, as defined in 40 CFR 761.3, for which
specification packagings are impractical, may be packaged in non-
specification packagings meeting the general packaging requirements of
subparts A and B of part 173 of this subchapter. Alternatively, the item
itself may be used as a packaging if it meets the general packaging
requirements of subparts A and B of part 173 of this subchapter.
101 The name of the particular substance or article must be specified.
102 The ends of the detonating cord must be tied fast so that the
explosive cannot escape.The articles may be transported as in Division
1.4 Compatibility Group D (1.4D) if all of the conditions specified in
Sec. 173.63(a) of this subchapter are met.
103 Detonators which will not mass detonate and undergo only limited
propagation in the shipping package may be assigned to 1.4B
classification code. Mass detonate means that more than 90 percent of
the devices tested in a package explode practically simultaneously.
Limited propagation means that if one detonator near the center of a
shipping package is exploded, the aggregate weight of explosives,
excluding ignition and delay charges, in this and all additional
detonators in the outside packaging that explode may not exceed 25
grams.
105 The word ``Agents'' may be used instead of ``Explosives'' when
approved by the Associate Administrator.
106 The recognized name of the particular explosive may be specified in
addition to the type.
107 The classification of the substance is expected to vary especially
with the particle size and packaging but the border lines have not been
experimentally determined; appropriate classifications should be
verified following the test procedures in Sec. Sec. 173.57 and 173.58
of this subchapter.
108 Fireworks must be so constructed and packaged that loose pyrotechnic
composition will not be present in packages during transportation.
109 Rocket motors must be nonpropulsive in transportation unless
approved in accordance with Sec. 173.56 of this subchapter. A rocket
motor to be considered ``nonpropulsive'' must be capable of unrestrained
burning and must not appreciably move in any direction when ignited by
any means.
110 Fire extinguishers transported under UN1044 may include installed
actuating cartridges (cartridges, power device of Division 1.4C or
1.4S), without changing the classification of Division 2.2, provided the
aggregate quantity of deflagrating (propellant) explosives does not
exceed 3.2 grams per extinguishing unit.
111 Explosive substances of Division 1.1 Compatibility Group A (1.1A)
are forbidden for transportation if dry or not desensitized, unless
incorporated in a device.
113 The sample must be given a tentative approval by an agency or
laboratory in accordance with Sec. 173.56 of this subchapter.
114 Jet perforating guns, charged, oil well, without detonator may be
reclassed to Division 1.4 Compatibility Group D (1.4D) if the following
conditions are met:
a. The total weight of the explosive contents of the shaped charges
assembled in the guns does not exceed 90.5 kg (200 pounds) per vehicle;
and
b. The guns are packaged in accordance with Packing Method US 1 as
specified in Sec. 173.62 of this subchapter.
115 Boosters with detonator, detonator assemblies and boosters with
detonators in which the total explosive charge per unit does not exceed
25 g, and which will not mass detonate and undergo only limited
propagation in the shipping package may be assigned to 1.4B
classification code. Mass detonate means more than 90 percent of the
devices tested in a package explode practically simultaneously. Limited
propagation means that if one booster near the center of the package is
exploded, the aggregate weight of explosives, excluding ignition and
delay charges, in this and all additional boosters in the outside
packaging that explode may not exceed 25 g.
116 Fuzes, detonating may be classed in Division 1.4 if the fuzes do not
contain more than 25 g of explosive per fuze and are made and packaged
so that they will not cause functioning of other fuzes, explosives or
other explosive devices if one of the fuzes detonates in a shipping
packaging or in adjacent packages.
117 If shipment of the explosive substance is to take place at a time
that freezing weather is anticipated, the water contained in the
explosive substance must be mixed with denatured alcohol so that
freezing will not occur.
118 This substance may not be transported under the provisions of
Division 4.1 unless specifically authorized by the Associate
Administrator.
119 This substance, when in quantities of not more than 11.5 kg (25.3
pounds), with not less than 10 percent water, by mass,
[[Page 322]]
also may be classed as Division 4.1, provided a negative test result is
obtained when tested in accordance with test series 6(c) of the UN
Manual of Tests and Criteria (IBR, see Sec. 171.7 of this subchapter).
120 The phlegmatized substance must be significantly less sensitive than
dry PETN.
121 This substance, when containing less alcohol, water or phlegmatizer
than specified, may not be transported unless approved by the Associate
Administrator.
123 Any explosives, blasting, type C containing chlorates must be
segregated from explosives containing ammonium nitrate or other ammonium
salts.
125 Lactose or glucose or similar materials may be used as a
phlegmatizer provided that the substance contains not less than 90%, by
mass, of phlegmatizer. These mixtures may be classified in Division 4.1
when tested in accordance with test series 6(c) of the UN Manual of
Tests and Criteria (IBR, see Sec. 171.7 of this subchapter) and
approved by the Associate Administrator. Testing must be conducted on at
least three packages as prepared for transport. Mixtures containing at
least 98%, by mass, of phlegmatizer are not subject to the requirements
of this subchapter. Packages containing mixtures with not less than 90%
by mass, of phlegmatizer need not bear a POISON subsidiary risk label.
127 Mixtures containing oxidizing and organic materials transported
under this entry may not meet the definition and criteria of a Class 1
material. (See Sec. 173.50 of this subchapter.)
128 Regardless of the provisions of Sec. 172.101(c)(12), aluminum
smelting by-products and aluminum remelting by-products described under
this entry, meeting the definition of Class 8, Packing Group II and III
may be classed as a Division 4.3 material and transported under this
entry. The presence of a Class 8 hazard must be communicated as required
by this Part for subsidiary hazards.
129 These materials may not be classified and transported unless
authorized by the Associate Administrator on the basis of results from
Series 2 Test and a Series 6(c) Test from the UN Manual of Tests and
Criteria (IBR, see Sec. 171.7 of this subchapter) on packages as
prepared for transport. The packing group assignment and packaging must
be approved by the Associate Administrator for Hazardous Materials
Safety on the basis of the criteria in Sec. 173.21 of this subchapter
and the package type used for the Series 6(c) test.
130 For other than a dry battery specifically covered by another entry
in the Sec. 172.101 Table, ``Batteries, dry'' are not subject to the
requirements of this subchapter when they are securely packaged and
offered for transportation in a manner that prevents the dangerous
evolution of heat (for example, by the effective insulation of exposed
terminals) and protects against short circuits.
131 This material may not be offered for transportation unless approved
by the Associate Administrator.
132 This entry may only be used for uniform, ammonium nitrate-base
fertilizer mixtures, containing nitrogen, phosphate or potash, meeting
the following criteria: (1) Contains not more than 70% ammonium nitrate;
and (2) Contains not more than 0.4% total combustible, organic material
calculated as carbon or with not more than 45% ammonium nitrate and
unrestricted combustible material. Fertilizers within these composition
limits are only subject to the requirements of this subchapter when
transported by aircraft or vessel, and are not subject to the
requirements of this subchapter if shown by a trough test, as specified
in the UN Manual of Tests and Criteria, Part III, Sub-section 38.2 (IBR,
see Sec. 171.7 of this subchapter), not to be liable to self-sustaining
decomposition.
134 This entry only applies to vehicles, machinery and equipment which
are powered by wet batteries, sodium batteries, or lithium batteries and
which are transported with these batteries installed. Examples of such
items are electrically-powered cars, lawn mowers, wheelchairs and other
mobility aids. A self-propelled vehicle which also contain an internal
combustion engine must be consigned under the entry ``Vehicle, flammable
gas powered'' or ``Vehicle, flammable liquid powered'', as appropriate.
135 The entries ``Vehicle, flammable gas powered'' or ``Vehicle,
flammable liquid powered'', as appropriate, must be used when internal
combustion engines are installed in a vehicle.
136 This entry only applies to machinery and apparatus containing
hazardous materials as in integral element of the machinery or
apparatus. It may not be used to describe machinery or apparatus for
which a proper shipping name exists in the Sec. 172.101 Table. Except
when approved by the Associate Administrator, machinery or apparatus may
only contain hazardous materials for which exceptions are referenced in
Column (8) of the Sec. 172.101 Table and are provided in part 173,
subpart D, of this subchapter. Hazardous materials shipped under this
entry are excepted from the labeling requirements of this subchapter
unless offered for transportation or transported by aircraft and are not
subject to the placarding requirements of part 172, subpart F, of this
subchapter. Orientation markings as described in Sec. 172.312 (a)(2)
are required when liquid hazardous materials may escape due to incorrect
orientation. The machinery or apparatus, if unpackaged, or the packaging
in which it is contained shall be marked ``Dangerous
[[Page 323]]
goods in machinery'' or ``Dangerous goods in apparatus'', as
appropriate, with the identification number UN3363. For transportation
by aircraft, machinery or apparatus may not contain any material
forbidden for transportation by passenger or cargo aircraft. The
Associate Administrator may except from the requirements of this
subchapter, equipment, machinery and apparatus provided:
a. It is shown that it does not pose a significant risk in
transportation;
b. The quantities of hazardous materials do not exceed those
specified in Sec. 173.4 of this subchapter; and
c. The equipment, machinery or apparatus conforms with Sec. 173.222
of this subchapter.
137 Cotton, dry, is not subject to the requirements of this subchapter
when it is baled in accordance with ISO 8115, ``Cotton Bales--Dimensions
and Density'' (IBR, see Sec. 171.7 of this subchapter) to a density of
at least 360 kg/m3 (22.4lb/ft3) and it is transported in a freight
container or closed transport vehicle.
138 Lead compounds which, when mixed in a ratio of 1:1000 with 0.07M
(Molar concentration) hydrochloric acid and stirred for one hour at a
temperature of 23 [deg]C 2 [deg]C, exhibit a
solubility of 5% or less are considered insoluble.
139 Use of the ``special arrangement'' proper shipping names for
international shipments must be made under an IAEA Certificate of
Competent Authority issued by the Associate Administrator in accordance
with the requirements in Sec. 173.471, Sec. 173.472, or Sec. 173.473
of this subchapter. Use of these proper shipping names for domestic
shipments may be made only under a DOT exemption, as defined in, and in
accordance with the requirements of subpart B of part 107 of this
subchapter.
140 This material is regulated only when it meets the defining criteria
for a hazardous substance or a marine pollutant. In addition, the column
5 reference is modified to read ``III'' on those occasions when this
material is offered for transportation or transported by highway or
rail.
141 A toxin obtained from a plant, animal, or bacterial source
containing an infectious substance, or a toxin contained in an
infectious substance, must be classed as Division 6.2, described as an
infectious substance, and assigned to UN 2814 or UN 2900, as
appropriate.
142 These hazardous materials may not be classified and transported
unless authorized by the Associate Administrator. The Associate
Administrator will base the authorization on results from Series 2 tests
and a Series 6(c) test from the UN Manual of Tests and Criteria (IBR,
see Sec. 171.7 of this subchapter) on packages as prepared for
transport in accordance with the requirements of this subchapter.
143 These articles may contain:
a. Division 2.2 compressed gases, including oxygen;
b. Signal devices (Class 1) which may include smoke and illumination
signal flares. Signal devices must be packed in plastic or fiberboard
inner packagings;
c. Electric storage batteries;
d. First aid kits; or
e. Strike anywhere matches.
144 If transported as a residue in an underground storage tank (UST), as
defined in 40 CFR 180.12, that has been cleaned and purged or rendered
inert according to the American Petroleum Institute (API) Standard 1604
(IBR, see Sec. 171.7 of this subchapter), then the tank and this
material are not subject to any other requirements of this subchapter.
However, sediments remaining in the tank that meet the definition for a
hazardous material are subject to the applicable regulations of this
subchapter.
145 This entry applies to formulations that neither detonate in the
cavitated state nor deflagrate in laboratory testing, show no effect
when heated under confinement, exhibit no explosive power, and are
thermally stable (self-accelerating decomposition temperature (SADT) at
60 [deg]C (140 [deg]F) or higher for a 50 kg (110.2 lbs.) package).
Formulations not meeting these criteria must be transported under the
provisions applicable to the appropriate entry in the Organic Peroxide
Table in Sec. 173.225 of this subchapter.
146 This description may be used for a material that poses a hazard to
the environment but does not meet the definition for a hazardous waste
or a hazardous substance, as defined in Sec. 171.8 of this subchapter,
or any hazard class as defined in Part 173 of this subchapter, if it is
designated as environmentally hazardous by the Competent Authority of
the country of origin, transit or destination.
147 This entry applies to non-sensitized emulsions, suspensions and gels
consisting primarily of a mixture of ammonium nitrate and a fuel
intended to produce a Type E blasting explosive only after further
processing. The mixture typically has the following composition: 60--85%
ammonium nitrate; 5--30% water; 2--8% fuel; 0.5--4% emulsifier or
thickening agent; 0--10% soluble flame suppressants; and trace
additives. Other inorganic nitrate salts may replace part of the
ammonium nitrate. These substances may not be classified and transported
unless approved by the Associate Administrator.
149 When transported as a limited quantity or a consumer commodity, the
maximum net capacity specified in Sec. 173.150(b)(2) of
[[Page 324]]
this subchapter for inner packagings may be increased to 5 L (1.3
gallons).
150 This description may be used only for uniform mixtures of
fertilizers containing ammonium nitrate as the main ingredient within
the following composition limits:
a. Not less than 90% ammonium nitrate with not more than 0.2% total
combustible, organic material calculated as carbon, and with added
matter, if any, that is inorganic and inert when in contact with
ammonium nitrate; or
b. Less than 90% but more than 70% ammonium nitrate with other
inorganic materials, or more than 80% but less than 90% ammonium nitrate
mixed with calcium carbonate and/or dolomite, and not more than 0.4%
total combustible, organic material calculated as carbon; or
c. Ammonium nitrate-based fertilizers containing mixtures of
ammonium nitrate and ammonium sulphate with more than 45% but less than
70% ammonium nitrate, and not more than 0.4% total combustible, organic
material calculated as carbon such that the sum of the percentage of
compositions of ammonium nitrate and ammonium sulphate exceeds 70%.
151 If this material meets the definition of a flammable liquid in Sec.
173.120 of this subchapter, a FLAMMABLE LIQUID label is also required
and the basic description on the shipping paper must indicate the Class
3 subsidiary hazard.
153 The following applies to aerosols:
a. Division 2.1 applies when the aerosol is flammable according to
Sec. 173.306(i) of this subchapter.
b. Division 2.2 applies when the contents of the aerosol do not meet
the criteria for Division 2.1, or Division 2.3.
c. Division 2.3 gases may not be used in an aerosol dispenser.
d. When the contents are classified as Division 6.1 or Class 8, the
aerosol must have a subsidiary risk of Division 6.1 or Class 8.
e. Aerosols with contents meeting the criteria for PG I and PG II
for Division 6.1 or Class 8 are forbidden for transportation.
f. Aerosols must meet the definition of aerosols in Sec. 171.8 of
this subchapter.
155 Fish meal or fish scrap may not be transported if the temperature at
the time of loading either exceeds 35 [deg]C (95 [deg]F), or exceeds 5
[deg]C (41 [deg]F) above the ambient temperature, whichever is higher.
156 Asbestos that is immersed or fixed in a natural or artificial binder
material, such as cement, plastic, asphalt, resins or mineral ore, or
contained in manufactured products is not subject to the requirements of
this subchapter.
157 This entry includes hybrid electric vehicles powered by both an
internal combustion engine and wet, sodium or lithium batteries,
transported with one or more batteries installed. Vehicles containing an
internal combustion engine must be described as ``Vehicle, flammable gas
powered,'' UN3166, or ``Vehicle, flammable liquid powered,'' UN3166, as
appropriate.
159 This material must be protected from direct sunshine and kept in a
cool, well-ventilated place away from sources of heat.
160 This entry applies to articles that are used as life-saving vehicle
air bag inflators, air bag modules or seat-belt pretensioners containing
Class 1 (explosive) materials or materials of other hazard classes. Air
bag inflators and modules must be tested in accordance with Test series
6(c) of Part I of the UN Manual of Tests and Criteria (incorporated by
reference; see Sec. 171.7 of this subchapter), with no explosion of the
device, no fragmentation of device casing or pressure vessel, and no
projection hazard or thermal effect that would significantly hinder
fire-fighting or other emergency response efforts in the immediate
vicinity. If the air bag inflator unit satisfactorily passes the series
6(c) test, it is not necessary to repeat the test on the air bag module.
161 For domestic transport, air bag inflators, air bag modules or seat
belt pretensioners that meet the criteria for a Division 1.4G explosive
must be transported using the description, ``Articles, pyrotechnic for
technical purposes,'' UN0431.
162 This material may be transported under the provisions of Division
4.1 only if it is packed so that at no time during transport will the
percentage of diluent fall below the percentage that is stated in the
shipping description.
(2) ``A'' codes. These provisions apply only to transportation by
aircraft:
Code/Special Provisions
A1 Single packagings are not permitted on passenger aircraft.
A2 Single packagings are not permitted on aircraft.
A3 For combination packagings, if glass inner packagings (including
ampoules) are used, they must be packed with absorbent material in
tightly closed metal receptacles before packing in outer packagings.
A4 Liquids having an inhalation toxicity of Packing Group I are not
permitted on aircraft.
A5 Solids having an inhalation toxicity of Packing Group I are not
permitted on passenger aircraft and may not exceed a maximum net
quantity per package of 15 kg (33 pounds) on cargo aircraft.
A6 For combination packagings, if plastic inner packagings are used,
they must be packed in tightly closed metal receptacles before packing
in outer packagings.
[[Page 325]]
A7 Steel packagings must be corrosion-resistant or have protection
against corrosion.
A8 For combination packagings, if glass inner packagings (including
ampoules) are used, they must be packed with cushioning material in
tightly closed metal receptacles before packing in outer packagings.
A9 For combination packagings, if plastic bags are used, they must be
packed in tightly closed metal receptacles before packing in outer
packagings.
A10 When aluminum or aluminum alloy construction materials are used,
they must be resistant to corrosion.
A11 For combination packagings, when metal inner packagings are
permitted, only specification cylinders constructed of metals which are
compatible with the hazardous material may be used.
A13 Bulk packagings are not authorized for transportation by aircraft.
A19 Combination packagings consisting of outer fiber drums or plywood
drums, with inner plastic packagings, are not authorized for
transportation by aircraft.
A20 Plastic bags as inner receptacles of combination packagings are not
authorized for transportation by aircraft.
A29 Combination packagings consisting of outer expanded plastic boxes
with inner plastic bags are not authorized for transportation by
aircraft.
A30 Ammonium permanganate is not authorized for transportation on
aircraft.
A34 Aerosols containing a corrosive liquid in Packing Group II charged
with a gas are not permitted for transportation by aircraft.
A35 This includes any material which is not covered by any of the other
classes but which has an anesthetic, narcotic, noxious or other similar
properties such that, in the event of spillage or leakage on an
aircraft, extreme annoyance or discomfort could be caused to crew
members so as to prevent the correct performance of assigned duties.
A37 This entry applies only to a material meeting the definition in
Sec. 171.8 of this subchapter for self-defense spray.
A51 When transported by cargo-only aircraft, an oxygen generator must
conform to the provisions of an approval issued under Special Provision
60 and be contained in a packaging prepared and originally offered for
transportation by the approval holder.
A52 A cylinder containing Oxygen, compressed, may not be loaded into a
passenger-carrying aircraft or into an inaccessible cargo location on a
cargo-only aircraft unless it is placed in an overpack or outer
packaging that conforms to the performance criteria of Air Transport
Association (ATA) Specification No. 300 (IBR, see Sec. 171.7 of this
subchapter) for Category I shipping containers.
A53 Refrigerating machines and refrigerating machine components are not
subject to the requirements of this subchapter when containing less than
12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3
gallons) or less of ammonia solution (UN2672) (see Sec. 173.307 of this
subchapter).
A54 Lithium batteries or lithium batteries contained or packed with
equipment that exceed the maximum gross weight allowed by Column (9B) of
the Sec. 172.101 Table may only be transported on cargo aircraft if
approved by the Associate Administrator.
A55 Prototype lithium batteries and cells that are packed with not more
than 24 cells or 12 batteries per packaging that have not completed the
test requirements in Sub-section 38.3 of the UN Manual of Tests and
Criteria (incorporated by reference; see Sec. 171.7 of this subchapter)
may be transported by cargo aircraft if approved by the Associate
Administrator and provided the following requirements are met:
a. The cells and batteries must be transported in rigid outer
packagings that conform to the requirements of Part 178 of this
subchapter at the Packing Group I performance level; and
b. Each cell and battery must be protected against short circuiting,
must be surrounded by cushioning material that is non-combustible and
non-conductive, and must be individually packed in an inner packaging
that is placed inside an outer specification packaging.
A56 Radioactive material with a subsidiary hazard of Division 4.2,
Packing Group I, must be transported in Type B packages when offered for
transportation by aircraft. Radioactive material with a subsidiary
hazard of Division 2.1 is forbidden from transport on passenger
aircraft.
A81 The quantity limits in columns (9A) and (9B) do not apply to body
fluids known to contain or suspected of containing an infectious
substance when transported in primary receptacles not exceeding 1,000 mL
(34 ounces) and in outer packagings not exceeding 4 L (1 gallon) and
packaged in accordance with Sec. 173.196 of this subchapter.
A82 The quantity limits in columns (9A) and (9B) do not apply to human
or animal body parts, whole organs or whole bodies known to contain or
suspected of containing an infectious substance.
(3) ``B'' codes. These provisions apply only to bulk packagings,
other than IBCs:
Code/Special Provisions
B1 If the material has a flash point at or above 38 [deg]C (100 [deg]F)
and below 93 [deg]C (200 [deg]F),
[[Page 326]]
then the bulk packaging requirements of Sec. 173.241 of this subchapter
are applicable. If the material has a flash point of less than 38 [deg]C
(100 [deg]F), then the bulk packaging requirements of Sec. 173.242 of
this subchapter are applicable.
B2 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo
tanks are not authorized.
B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo
tanks and DOT 57 portable tanks are not authorized.
B4 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo
tanks are not authorized.
B5 Only ammonium nitrate solutions with 35 percent or less water that
will remain completely in solution under all conditions of transport at
a maximum lading temperature of 116 [deg]C (240 [deg]F) are authorized
for transport in the following bulk packagings: MC 307, MC 312, DOT 407
and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure.
The packaging shall be designed for a working temperature of at least
121 [deg]C (250 [deg]F). Only Specifications MC 304, MC 307 or DOT 407
cargo tank motor vehicles are authorized for transportation by vessel.
B6 Packagings shall be made of steel.
B7 Safety relief devices are not authorized on multi-unit tank car
tanks. Openings for safety relief devices on multi-unit tank car tanks
shall be plugged or blank flanged.
B8 Packagings shall be made of nickel, stainless steel, or steel with
nickel, stainless steel, lead or other suitable corrosion resistant
metallic lining.
B9 Bottom outlets are not authorized.
B10 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo
tanks, and DOT 57 portable tanks are not authorized.
B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa
(300 psig). Cargo and portable tanks must have a design pressure of at
least 1,207 kPa (175 psig).
B13 A nonspecification cargo tank motor vehicle authorized in Sec.
173.247 of this subchapter must be at least equivalent in design and in
construction to a DOT 406 cargo tank or MC 306 cargo tank (if
constructed before August 31, 1995), except as follows:
a. Packagings equivalent to MC 306 cargo tanks are excepted from the
certification, venting, and emergency flow requirements of the MC 306
specification.
b. Packagings equivalent to DOT 406 cargo tanks are excepted from
Sec. Sec. 178.345-7(d)(5), circumferential reinforcements; 178.345-10,
pressure relief; 178.345-11, outlets; 178.345-14, marking, and 178.345-
15, certification.
c. Packagings are excepted from the design stress limits at elevated
temperatures, as described in Section VIII of the ASME Code (IBR, see
Sec. 171.7 of this subchapter). However, the design stress limits may
not exceed 25 percent of the stress for 0 temper at the maximum design
temperature of the cargo tank, as specified in the Aluminum
Association's ``Aluminum Standards and Data'' (IBR, see Sec. 171.7 of
this subchapter).
B14 Each bulk packaging, except a tank car or a multi-unit-tank car
tank, must be insulated with an insulating material so that the overall
thermal conductance at 15.5 [deg]C (60 [deg]F) is no more than 1.5333
kilojoules per hour per square meter per degree Celsius (0.075 Btu per
hour per square foot per degree Fahrenheit) temperature differential.
Insulating materials must not promote corrosion to steel when wet.
B15 Packagings must be protected with non-metallic linings impervious to
the lading or have a suitable corrosion allowance.
B16 The lading must be completely covered with nitrogen, inert gas or
other inert materials.
B18 Open steel hoppers or bins are authorized.
B23 Tanks must be made of steel that is rubber lined or unlined. Unlined
tanks must be passivated before being placed in service. If unlined
tanks are washed out with water, they must be repassivated prior to
return to service. Lading in unlined tanks must be inhibited so that the
corrosive effect on steel is not greater than that of hydrofluoric acid
of 65 percent concentration.
B25 Packagings must be made from monel or nickel or monel-lined or
nickel-lined steel.
B26 Tanks must be insulated. Insulation must be at least 100 mm (3.9
inches) except that the insulation thickness may be reduced to 51 mm (2
inches) over the exterior heater coils. Interior heating coils are not
authorized. The packaging may not be loaded with a material outside of
the packaging's design temperature range. In addition, the material also
must be covered with an inert gas or the container must be filled with
water to the tank's capacity. After unloading, the residual material
also must be covered with an inert gas or the container must be filled
with water to the tank's capacity.
B27 Tanks must have a service pressure of 1,034 kPa (150 psig). Tank car
tanks must have a test pressure rating of 1,379 kPa (200 psig). Lading
must be blanketed at all times with a dry inert gas at a pressure not to
exceed 103 kPa (15 psig).
B28 Packagings must be made of stainless steel.
B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable
tanks must be made of stainless steel, except that steel other than
stainless steel may be used in accordance with the provisions
[[Page 327]]
of Sec. 173.24b(b) of this subchapter. Thickness of stainless steel for
tank shell and heads for cargo tanks and portable tanks must be the
greater of 7.62 mm (0.300 inch) or the thickness required for a tank
with a design pressure at least equal to 1.5 times the vapor pressure of
the lading at 46 [deg]C (115 [deg]F). In addition, MC 312 and DOT 412
cargo tank motor vehicles must:
a. Be ASME Code (U) stamped for 100% radiography of all pressure-
retaining welds;
b. Have accident damage protection which conforms with Sec.
178.345-8 of this subchapter;
c. Have a MAWP or design pressure of at least 87 psig: and
d. Have a bolted manway cover.
B32 MC 312, MC 330, MC 331, DOT 412 cargo tanks and DOT 51 portable
tanks must be made of stainless steel, except that steel other than
stainless steel may be used in accordance with the provisions of Sec.
173.24b(b) of this subchapter. Thickness of stainless steel for tank
shell and heads for cargo tanks and portable tanks must be the greater
of 6.35 mm (0.250 inch) or the thickness required for a tank with a
design pressure at least equal to 1.3 times the vapor pressure of the
lading at 46 [deg]C (115 [deg]F). In addition, MC 312 and DOT 412 cargo
tank motor vehicles must:
a. Be ASME Code (U) stamped for 100% radiography of all pressure-
retaining welds;
b. Have accident damage protection which conforms with Sec. 178.345-8
of this subchapter;
c. Have a MAWP or design pressure of at least 87 psig; and
d. Have a bolted manway cover.
B33 MC 300, MC 301, MC 302, MC 303, MC 305, MC 306, and DOT 406 cargo
tanks equipped with a 1 psig normal vent used to transport gasoline must
conform to Table I of this Special Provision. Based on the volatility
class determined by using ASTM D 439 and the Reid vapor pressure (RVP)
of the particular gasoline, the maximum lading pressure and maximum
ambient temperature permitted during the loading of gasoline may not
exceed that listed in Table I.
Table I--Maximum Ambient Temperature--Gasoline
------------------------------------------------------------------------
Maximum lading and ambient
ASTM D439 volatility class temperature (see note 1)
------------------------------------------------------------------------
A...................................... 131 [deg]F
(RVP<=9.0 psia)
B...................................... 124 [deg]F
(RVP<=10.0 psia)
C...................................... 116 [deg]F
(RVP<=11.5 psia)
D...................................... 107 [deg]F
(RVP<=13.5 psia)
E...................................... 100 [deg]F
(RVP<=15.0 psia)
------------------------------------------------------------------------
Note 1: Based on maximum lading pressure of 1 psig at top of cargo
tank.
B35 Tank cars containing hydrogen cyanide may be alternatively marked
``Hydro cyanic acid, liquefied'' if otherwise conforming to marking
requirements in subpart D of this part. Tank cars marked ``HYDROCYANIC
ACID'' prior to October 1, 1991 do not need to be remarked.
B37 The amount of nitric oxide charged into any tank car tank may not
exceed 1,379 kPa (200 psig) at 21 [deg]C (70 [deg]F).
B42 Tank cars must have a test pressure of 34.47 Bar (500 psig) or
greater and conform to Class 105J. Each tank car must have a reclosing
pressure relief device having a start-to-discharge pressure of 10.34 Bar
(150 psig). The tank car specification may be marked to indicate a test
pressure of 13.79 Bar (200 psig).
B44 All parts of valves and safety relief devices in contact with lading
must be of a material which will not cause formation of acetylides.
B45 Each tank must have a reclosing combination pressure relief device
equipped with stainless steel or platinum rupture discs approved by the
AAR Tank Car Committee.
B46 The detachable protective housing for the loading and unloading
valves of multi-unit tank car tanks must withstand tank test pressure
and must be approved by the Associate Administrator.
B47 Each tank may have a reclosing pressure relief device having a
start-to-discharge pressure setting of 310 kPa (45 psig).
B48 Portable tanks in sodium metal service may be visually inspected at
least once every 5 years instead of being retested hydrostatically. Date
of the visual inspection must be stenciled on the tank near the other
required markings.
B49 Tanks equipped with interior heater coils are not authorized. Single
unit tank car tanks must have a reclosing pressure relief device having
a start-to-discharge pressure set at no more than 1551 kPa (225 psig).
B50 Each valve outlet of a multi-unit tank car tank must be sealed by a
threaded solid plug or a threaded cap with inert luting or gasket
material. Valves must be of stainless steel and the caps, plugs, and
valve seats must be of a material that will not deteriorate as a result
of contact with the lading.
B52 Notwithstanding the provisions of Sec. 173.24b of this subchapter,
non-reclosing
[[Page 328]]
pressure relief devices are authorized on DOT 57 portable tanks.
B53 Packagings must be made of either aluminum or steel.
B54 Open-top, sift-proof rail cars are also authorized.
B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars,
equipped with a venting arrangement (including flame arrestors) approved
by the Associate Administrator are also authorized.
B56 Water-tight, sift-proof, closed-top, metal-covered hopper cars are
also authorized if the particle size of the hazardous material is not
less than 149 microns.
B57 Class 115A tank car tanks used to transport chloroprene must be
equipped with a non-reclosing pressure relief device of a diameter not
less than 305 mm (12 inches) with a maximum rupture disc pressure of 310
kPa (45 psig).
B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are
also authorized provided that the lading is covered with a nitrogen
blanket.
B60 DOT Specification 106A500X multi-unit tank car tanks that are not
equipped with a pressure relief device of any type are authorized. For
the transportation of phosgene, the outage must be sufficient to prevent
tanks from becoming liquid full at 55 [deg]C (130 [deg]F).
B61 Written procedures covering details of tank car appurtenances, dome
fittings, safety devices, and marking, loading, handling, inspection,
and testing practices must be approved by the Associate Administrator
before any single unit tank car tank is offered for transportation.
B64 Each single unit tank car tank built after December 31, 1990 must be
equipped with a tank head puncture resistance system that conforms to
Sec. 179.16 of this subchapter.
B65 Tank cars must have a test pressure of 34.47 Bar (500 psig) or
greater and conform to Class 105A. Each tank car must have a pressure
relief device having a start-to-discharge pressure of 15.51 Bar (225
psig). The tank car specification may be marked to indicate a test
pressure of 20.68 Bar (300 psig).
B66 Each tank must be equipped with gas tight valve protection caps.
Outage must be sufficient to prevent tanks from becoming liquid full at
55 [deg]C (130 [deg]F). Specification 110A500W tanks must be stainless
steel.
B67 All valves and fittings must be protected by a securely attached
cover made of metal not subject to deterioration by the lading, and all
valve openings, except safety valve, must be fitted with screw plugs or
caps to prevent leakage in the event of valve failure.
B68 Sodium must be in a molten condition when loaded and allowed to
solidify before shipment. Outage must be at least 5 percent at 98 [deg]C
(208 [deg]F). Bulk packagings must have exterior heating coils fusion
welded to the tank shell which have been properly stress relieved. The
only tank car tanks authorized are Class DOT 105 tank cars having a test
pressure of 2,069 kPa (300 psig) or greater.
B69 Dry sodium cyanide or potassium cyanide may be shipped in sift-proof
weather-resistant metal covered hopper cars, covered motor vehicles,
portable tanks or non-specification bins. Siftproof, water-resistant,
fiberboard IBCs are permitted when transported in closed freight
containers or transport vehicles. Bins must be approved by the Associate
Administrator.
B70 If DOT 103ANW tank car tank is used: All cast metal in contact with
the lading must have 96.7 percent nickel content; and the lading must be
anhydrous and free from any impurities.
B71 Tank cars must have a test pressure of 20.68 Bar (300 psig) or
greater and conform to Class 105, 112, 114 or 120.
B72 Tank cars must have a test pressure of 34.47 Bar (500 psig) or
greater and conform to Class 105J, 106, or 110.
B74 Tank cars must have a test pressure of 20.68 Bar (300 psig) or
greater and conform to Class 105S, 106, 110, 112J, 114J or 120S.
B76 Tank cars must have a test pressure of 20.68 Bar (300 psig) or
greater and conform to Class 105S, 112J, 114J or 120S. Each tank car
must have a reclosing pressure relief device having a start-to-discharge
pressure of 10.34 Bar (150 psig). The tank car specification may be
marked to indicate a test pressure of 13.79 Bar (200 psig).
B77 Other packaging are authorized when approved by the Associate
Administrator.
B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater
and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. Heater
pipes must be of welded construction designed for a test pressure of 500
psig. A 25 mm (1 inch) woven lining of asbestos or other approved
material must be placed between the bolster slabbing and the bottom of
the tank. If a tank car tank is equipped with a non-reclosing pressure
relief device, the rupture disc must be perforated with a 3.2 mm (0.13
inch) diameter hole. If a tank car tank is equipped with a reclosing
pressure relief valve, the tank must also be equipped with a vacuum
relief valve.
B80 Each cargo tank must have a minimum design pressure of 276 kPa (40
psig).
B81 Venting and pressure relief devices for tank car tanks and cargo
tanks must be approved by the Associate Administrator.
B82 Cargo tanks and portable tanks are not authorized.
B83 Bottom outlets are prohibited on tank car tanks transporting
sulfuric acid in concentrations over 65.25 percent.
[[Page 329]]
B84 Packagings must be protected with non-metallic linings impervious to
the lading or have a suitable corrosion allowance for sulfuric acid or
spent sulfuric acid in concentration up to 65.25 percent.
B85 Cargo tanks must be marked with the name of the lading in accordance
with the requirements of Sec. 172.302(b).
B90 Steel tanks conforming or equivalent to ASME specifications which
contain solid or semisolid residual motor fuel antiknock mixture
(including rust, scale, or other contaminants) may be shipped by rail
freight or highway. The tank must have been designed and constructed to
be capable of withstanding full vacuum. All openings must be closed with
gasketed blank flanges or vapor tight threaded closures.
B115 Rail cars, highway trailers, roll-on/roll-off bins, or other non-
specification bulk packagings are authorized. Packagings must be sift-
proof, prevent liquid water from reaching the hazardous material, and be
provided with sufficient venting to preclude dangerous accumulation of
flammable, corrosive, or toxic gaseous emissions such as methane,
hydrogen, and ammonia. The material must be loaded dry.
(4) Table 1, Table 2, and Table 3--IB Codes, Organic Peroxide IBC
Code, and IP Special IBC Packing Provisions. These provisions apply only
to transportation in IBCs. When no IBC code is assigned in the Sec.
172.101 Table for a specific proper shipping name, an IBC may be
authorized when approved by the Associate Administrator. When only
certain types of IBCs are authorized in Table 2 (IBC Code IB52),
alternative types of IBCs may be authorized when approved by the
Associate Administrator. The letter ``Z'' shown in the marking code for
composite IBCs must be replaced with a capital code letter designation
found in Sec. 178.702(a)(2) of this subchapter to specify the material
used for the outer packaging. Tables 1, 2, and 3 follow:
Table 1--IB Codes (IBC Codes)
------------------------------------------------------------------------
IBC Code Authorized IBCs
------------------------------------------------------------------------
IB1.................... Authorized IBCs: Metal (31A, 31B and 31N).
Additional Requirement: Only liquids with a
vapor pressure less than or equal to 110 kPa
at 50 [deg]C (1.1 bar at 122 [deg]F), or 130
kPa at55 [deg]C (1.3 bar at 131 [deg]F) are
authorized.
IB2.................... Authorized IBCs: Metal (31A, 31B and 31N);
Rigid plastics (31H1 and 31H2); Composite
(31HZ1).
Additional Requirement: Only liquids with a
vapor pressure less than or equal to 110 kPa
at 50 [deg]C (1.1 bar at 122 [deg]F), or
130kPa at 55 [deg]C (1.3 bar at 131 [deg]F)
are authorized.
IB3.................... Authorized IBCs: Metal (31A, 31B and 31N);
Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and
31HH2).
Additional Requirement: Only liquids with a
vapor pressure less than or equal to 110 kPa
at 50 [deg]C (1.1 bar at 122 [deg]F), or 130
kPa at 55 [deg]C (1.3 bar at 131 [deg]F) are
authorized, except for UN2672 (also see
Special Provision IP8 in Table 3 for UN2672).
IB4.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A,
21B, 21N, 31A, 31B and 31N).
IB5.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A,
21B, 21N, 31A, 31B and 31N); Rigid plastics
(11H1, 11H2, 21H1, 21H2, 31H1 and 31H2);
Composite (11HZ1, 21HZ1 and 31HZ1).
IB6.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A,
21B, 21N, 31A, 31B and 31N); Rigid plastics
(11H1, 11H2, 21H1, 21H2, 31H1 and 31H2);
Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1
and 31HZ2).
Additional Requirement: Composite IBCs 11HZ2
and 21HZ2 may not be used when the hazardous
materials being transported may become liquid
during transport.
IB7.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A,
21B, 21N, 31A, 31B and 31N); Rigid plastics
(11H1, 11H2, 21H1, 21H2, 31H1 and 31H2);
Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1
and 31HZ2); Wooden (11C, 11D and 11F).
Additional Requirement: Liners of wooden IBCs
must be sift-proof.
IB8.................... Authorized IBCs: Metal (11A, 11B, 11N, 21A,
21B, 21N, 31A, 31B and 31N); Rigid plastics
(11H1, 11H2, 21H1, 21H2, 31H1 and 31H2);
Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1
and 31HZ2); Fiberboard (11G); Wooden (11C, 11D
and 11F); Flexible (13H1, 13H2, 13H3, 13H4,
13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).
IB99................... IBCs are only authorized if approved by the
Associate Administrator.
------------------------------------------------------------------------
Table 2--Organic Peroxide IBC Code (IB52)
----------------------------------------------------------------------------------------------------------------
Maximum
UN No. Organic peroxide Type of IBC quantity Control Emergency
(liters) temperature temperature
----------------------------------------------------------------------------------------------------------------
3109............... ORGANIC PEROXIDE,
TYPE F, LIQUID
tert-Butyl 31A 1250
hydroperoxide, not
more than 72% with
water.
tert-Butyl 31A 1250
peroxyacetate, not 31HA1 1000
more than 32% in
diluent type A.
[[Page 330]]
tert-Butyl peroxy- 31A 1250
3,5,5- 31HA1 1000
trimethylhexanoate
, not more than
32% in diluent
type A.
Cumyl 31HA1 1250
hydroperoxide, not
more than 90% in
diluent type A.
Dibenzoyl peroxide, 31H1 1000
not more than 42%
as a stable
dispersion.
Dicumyl peroxide, 31A 1250
less than or equal 31HA1 1000
to 100%.
Di-tert-butyl 31A 1250
peroxide, not more 31HA1 1000
than 52% on
diluent type B.
1,1-Di-(tert- 31H1 1000
butylperoxy)
cyclohexane, not
more than 42% in
diluent type A.
Dilauroyl peroxide, 31HA1 1000
not more than 42%,
stable dispersion,
in water.
Isopropyl cumyl 31HA1 1250
hydroperoxide, not
more than 72% in
diluent type A.
p-Menthyl 31HA1 1250
hydroperoxide, not
more than 72% in
diluent type A.
Peroxyacetic acid, 31H1 1500
stabilized, not 31HA1 1500
more than 17%. 31A 1500
Peroxyacetic acid, 31A 1500
with not more than 31HA1 1500
26% hydrogen
peroxide.
Peroxyacetic acid, 31A 1500
type F, stabilized. 31HA1 1500
3110............... Dicumyl peroxide, 31A 2000
less than or equal 31H1
to 100%. 31HA1
3119............... ORGANIC PEROXIDE,
TYPE F, LIQUID,
TEMPERATURE
CONTROLLED
tert-Butyl peroxy-2- 31HA1 1000 +30 [deg]C +35 [deg]C
ethylhexanoate, 31A 1250 +30 [deg]C +35 [deg]C
not more than 32%
in diluent type B.
tert-Butyl 31A 1250 0 [deg]C +10 [deg]C
peroxyneodecanoate
, not more than
32% in diluent
type A.
tert-Butyl 31A 1250 -5 [deg]C +5 [deg]C
peroxyneodecanoate
, not more than
42% stable
dispersion, in
water.
tert-Butyl 31HA1 1000 +10 [deg]C +15 [deg]C
peroxypivalate, 31A 1250 +10 [deg]C +15 [deg]C
not more than 27%
in diluent type B.
Cumyl 31A 1250 -15 [deg]C -5 [deg]C
peroxyneodecanoate
, not more than
52%, stable
dispersion, in
water.
Di-(4-tert- 31HA1 1000 +30 [deg]C +35 [deg]C
butylcyclohexyl)
peroxydicarbonate,
not more than 42%,
stable dispersion,
in water.
Dicetyl 31HA1 1000 +30 [deg]C +35 [deg]C
peroxydicarbonate,
not more than 42%,
stable dispersion,
in water.
Di-(2-ethylhexyl) 31A 1250 -20 [deg]C -10 [deg]C
peroxydicarbonate,
not more than 52%,
stable dispersion,
in water.
Dimyristyl 31HA1 1000 +15 [deg]C +20 [deg]C
peroxydicarbonate,
not more than 42%,
stable dispersion,
in water.
Di-(3,5,5- 31HA1 1000 +10 [deg]C +15 [deg]C
trimethylhexanoyl) 31A 1250 +10 [deg]C +15 [deg]C
peroxide, not more
than 38% in
diluent type A.
Di-(3,5,5- 31A 1250 +10 [deg]C +15 [deg]C
trimethylhexanoyl)
peroxide, not more
than 52%, stable
dispersion, in
water.
1,1,3,3- 31A 1250 -5 [deg]C +5 [deg]C
Tetramethylbutyl
peroxyneodecanoate
, not more than
52%, stable
dispersion, in
water.
----------------------------------------------------------------------------------------------------------------
Table 3--IP Codes
------------------------------------------------------------------------
-------------------------------------------------------------------------
IP1 IBCs must be packed in closed freight containers or a closed
transport vehicle.
IP2 When IBCs other than metal or rigid plastics IBCs are used, they
must be offered for transportation in a closed freight container or a
closed transport vehicle.
IP3 Flexible IBCs must be sift-proof and water-resistant or must be
fitted with a sift-proof and water-resistant liner.
[[Page 331]]
IP4 Flexible, fiberboard or wooden IBCs must be sift-proof and water-
resistant or be fitted with a sift-proof and water-resistant liner.
IP5 IBCs must have a device to allow venting. The inlet to the venting
device must be located in the vapor space of the IBC under maximum
filling conditions.
IP6 Non-specification bulk bins are authorized.
IP7 For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841,
2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC
performance tests specified in part 178, subpart N of this subchapter.
IP8 Ammonia solutions may be transported in rigid or composite plastic
IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without
leakage or permanent deformation, the hydrostatic test specified in
Sec. 178.814 of this subchapter at a test pressure that is not less
than 1.5 times the vapor pressure of the contents at 55 [deg]C (131
[deg]F).
------------------------------------------------------------------------
(5) ``N'' codes. These provisions apply only to non-bulk packagings:
Code/Special Provisions
N3 Glass inner packagings are permitted in combination or composite
packagings only if the hazardous material is free from hydrofluoric
acid.
N4 For combination or composite packagings, glass inner packagings,
other than ampoules, are not permitted.
N5 Glass materials of construction are not authorized for any part of a
packaging which is normally in contact with the hazardous material.
N6 Battery fluid packaged with electric storage batteries, wet or dry,
must conform to the packaging provisions of Sec. 173.159 (g) or (h) of
this subchapter.
N7 The hazard class or division number of the material must be marked on
the package in accordance with Sec. 172.302 of this subchapter.
However, the hazard label corresponding to the hazard class or division
may be substituted for the marking.
N8 Nitroglycerin solution in alcohol may be transported under this entry
only when the solution is packed in metal cans of not more than 1 L
capacity each, overpacked in a wooden box containing not more than 5 L.
Metal cans must be completely surrounded with absorbent cushioning
material. Wooden boxes must be completely lined with a suitable material
impervious to water and nitroglycerin.
N10 Lighters and their inner packagings, which have been approved by the
Associate Administrator (see Sec. 173.21(i) of this subchapter), must
be packaged in one of the following outer packagings at the Packing
Group II level: 4C1 or 4C2 wooden boxes; 4D plywood boxes; 4F
reconstituted wood boxes; 4G fiberboard boxes; or 4H1 or 4H2 plastic
boxes. The approval number (e.g., T-* * *) must be marked on each outer
package and on the shipping paper.
N11 This material is excepted for the specification packaging
requirements of this subchapter if the material is packaged in strong,
tight non-bulk packaging meeting the requirements of subparts A and B of
part 173 of this subchapter.
N12 Plastic packagings are not authorized.
N20 A 5M1 multi-wall paper bag is authorized if transported in a closed
transport vehicle.
N25 Steel single packagings are not authorized.
N32 Aluminum materials of construction are not authorized for single
packagings.
N33 Aluminum drums are not authorized.
N34 Aluminum construction materials are not authorized for any part of a
packaging which is normally in contact with the hazardous material.
N36 Aluminum or aluminum alloy construction materials are permitted only
for halogenated hydrocarbons that will not react with aluminum.
N37 This material may be shipped in an integrally-lined fiber drum (1G)
which meets the general packaging requirements of subpart B of part 173
of this subchapter, the requirements of part 178 of this subchapter at
the packing group assigned for the material and to any other special
provisions of column 7 of the Sec. 172.101 table.
N40 This material is not authorized in the following packagings:
a. A combination packaging consisting of a 4G fiberboard box with
inner receptacles of glass or earthenware;
b. A single packaging of a 4C2 sift-proof, natural wood box; or
c. A composite packaging 6PG2 (glass, porcelain or stoneware
receptacles within a fiberboard box).
N41 Metal construction materials are not authorized for any part of a
packaging which is normally in contact with the hazardous material.
N42 1A1 drums made of carbon steel with thickness of body and heads of
not less than 1.3 mm (0.050 inch) and with a corrosion-resistant
phenolic lining are authorized for stabilized benzyl chloride if tested
[[Page 332]]
and certified to the Packing Group I performance level at a specific
gravity of not less than 1.8.
N43 Metal drums are permitted as single packagings only if constructed
of nickel or monel.
N45 Copper cartridges are authorized as inner packagings if the
hazardous material is not in dispersion.
N65 Outage must be sufficient to prevent cylinders or spheres from
becoming liquid full at 55 [deg]C (130 [deg]F). The vacant space
(outage) may be charged with a nonflammable nonliquefied compressed gas
if the pressure in the cylinder or sphere at 55 [deg]C (130 [deg]F) does
not exceed 125 percent of the marked service pressure.
N72 Packagings must be examined by the Bureau of Explosives and approved
by the Associate Administrator.
N73 Packagings consisting of outer wooden or fiberboard boxes with inner
glass, metal or other strong containers; metal or fiber drums; kegs or
barrels; or strong metal cans are authorized and need not conform to the
requirements of part 178 of this subchapter.
N74 Packages consisting of tightly closed inner containers of glass,
earthenware, metal or polyethylene, capacity not over 0.5 kg (1.1
pounds) securely cushioned and packed in outer wooden barrels or wooden
or fiberboard boxes, not over 15 kg (33 pounds) net weight, are
authorized and need not conform to the requirements of part 178 of this
subchapter.
N75 Packages consisting of tightly closed inner packagings of glass,
earthenware or metal, securely cushioned and packed in outer wooden
barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5
pounds) net weight, are authorized and need not conform to the
requirements of part 178 of this subchapter.
N76 For materials of not more than 25 percent active ingredient by
weight, packages consisting of inner metal packagings not greater than
250 mL (8 ounces) capacity each, packed in strong outer packagings
together with sufficient absorbent material to completely absorb the
liquid contents are authorized and need not conform to the requirements
of part 178 of this subchapter.
N77 For materials of not more than two percent active ingredients by
weight, packagings need not conform to the requirements of part 178 of
this subchapter, if liquid contents are absorbed in an inert material.
N78 Packages consisting of inner glass, earthenware, or polyethylene or
other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds)
capacity each, or metal cans not over five pounds capacity each, packed
in outer wooden boxes, barrels or kegs, or fiberboard boxes are
authorized and need not conform to the requirements of part 178 of this
subchapter. Net weight of contents in fiberboard boxes may not exceed 29
kg (64 pounds). Net weight of contents in wooden boxes, barrels or kegs
may not exceed 45 kg (99 pounds).
N79 Packages consisting of tightly closed metal inner packagings not
over 0.5 kg (1.1 pounds) capacity each, packed in outer wooden or
fiberboard boxes, or wooden barrels, are authorized and need not conform
to the requirements of part 178 of this subchapter. Net weight of
contents may not exceed 15 kg (33 pounds).
N80 Packages consisting of one inner metal can, not over 2.5 kg (5.5
pounds) capacity, packed in an outer wooden or fiberboard box, or a
wooden barrel, are authorized and need not conform to the requirements
of part 178 of this subchapter.
N82 See Sec. 173.306 of this subchapter for classification criteria for
flammable aerosols.
N83 This material may not be transported in quantities of more than 11.5
kg (25.4 lbs) per package.
N84 The maximum quantity per package is 500 g (1.1 lbs.).
N85 Packagings certified at the Packing Group I performance level may
not be used.
(6) ``R'' codes. These provisions apply only to transportation by
rail. [Reserved]
(7) ``T'' codes. (i) These provisions apply to the transportation of
hazardous materials in UN and IM Specification portable tanks. Portable
tank instructions specify the requirements applicable to a portable tank
when used for the transportation of a specific hazardous material. These
requirements must be met in addition to the design and construction
specifications in part 178 of this subchapter. Portable tank
instructions T1 through T22 specify the applicable minimum test
pressure, the minimum shell thickness (in reference steel), bottom
opening requirements and pressure relief requirements. In T23, the
organic peroxides and self-reactive substances which are authorized to
be transported in portable tanks are listed along with the applicable
control and emergency temperatures. Liquefied compressed gases are
assigned to portable tank instruction T50. T50 provides the maximum
allowable working pressures, bottom opening requirements, pressure
relief requirements and degree of filling requirements for liquefied
compressed
[[Page 333]]
gases permitted for transport in portable tanks. Refrigerated liquefied
gases which are authorized to be transported in portable tanks are
specified in tank instruction T75.
(ii) The following table specifies the portable tank requirements
applicable to T Codes T1 through T22. Column 1 specifies the T Code.
Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5
psig), at which the periodic hydrostatic testing required by Sec.
180.605 of this subchapter must be conducted. Column 3 specifies the
section reference for minimum shell thickness or, alternatively, the
minimum shell thickness value. Column 4 specifies the applicability of
Sec. 178.275(g)(3) of this subchapter for the pressure relief devices.
When the word ``Normal'' is indicated, Sec. 178.275(g)(3) of this
subchapter does not apply. Column 5 references the applicable
requirements for bottom openings in part 178 of this subchapter or
references ``Prohibited'' which means bottom openings are prohibited.
The table follows:
Table of Portable Tank T Coder T1-T22
[Portable tank code T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are
transported in portable tanks.]
----------------------------------------------------------------------------------------------------------------
Minimum test Minimum shell thickness Pressure-relief Bottom opening
Portable tank pressure (in mm-reference steel) requirements (See requirements (See Sec.
instruction (bar) (See Sec. 178.274(d)) Sec. 178.275(g)) 178.275(d))
(1) (2) (3) (4)............... (5)
---------------------
T1.................. 1.5 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(2).
T2.................. 1.5 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3).
T3.................. 2.65 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(2).
T4.................. 2.65 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3).
T5.................. 2.65 Sec. 178.274(d)(2) Sec. Prohibited.
178.275(g)(3).
T6.................. 4 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(2).
T7.................. 4 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3).
T8.................. 4 Sec. 178.274(d)(2) Normal............ Prohibited.
T9.................. 4 6 mm Normal............ Prohibited.
T10................. 4 6 mm Sec. Prohibited.
178.275(g)(3).
T11................. 6 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3).
T12................. 6 Sec. 178.274(d)(2) Sec. Sec. 178.275(d)(3).
178.275(g)(3).
T13................. 6 6 mm Normal............ Prohibited.
T14................. 6 6 mm Sec. Prohibited.
178.275(g)(3).
T15................. 10 Sec. 178.274(d)(2) Normal............ Sec. 178.275(d)(3).
T16................. 10 Sec. 178.274(d)(2) Sec. Sec. 178.275(d)(3).
178.275(g)(3).
T17................. 10 6 mm Normal............ Sec. 178.275(d)(3).
T18................. 10 6 mm Sec. Sec. 178.275(d)(3).
178.275(g)(3).
T19................. 10 6 mm Sec. Prohibited.
178.275(g)(3).
T20................. 10 8 mm Sec. Prohibited.
178.275(g)(3).
T21................. 10 10 mm Normal............ Prohibited.
T22................. 10 10 mm Sec. Prohibited.
178.275(g)(3).
----------------------------------------------------------------------------------------------------------------
(iii) The following table specifies the portable tank requirements
applicable to T23 for self-reactive substances of Division 4.1 and
organic peroxides of Division 5.2 which are authorized to be transported
in portable tanks:
[[Page 334]]
Portable Tank Code T23
[Portable tank code T23 applies to self-reactive substances of Division 4.1 and organic peroxides of Division 5.2.]
--------------------------------------------------------------------------------------------------------------------------------------------------------
Minimum Minimum shell
Hazardous test thickness (mm- Bottom opening Pressure-relief Control Emergency
UN No. material pressure reference steel) requirements See requirements See Filling limits tempereature temperature
(bar) See . . . . . . . . .
--------------------------------------------------------------------------------------------------------------------------------------------------------
3109 Organic peroxide, 4 Sec. Sec. Sec. Not more than
Type F, liquid 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
[deg]F (15
[deg]C)
tert-Butyl 4 Sec. Sec. Sec. Not more than
hydroperoxide, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
not more than [deg]F (15
72% with water. [deg]C)
*Provided that
steps have been
taken to achieve
the safety
equivalence of
65% tert-Butyl
hydroperoxide
and 35% water
Cumyl hydro- 4 Sec. Sec. Sec. Not more than
peroxide, not 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
more than 90% in [deg]F (15
diluent type A [deg]C)
Dicumyl peroxide, 4 Sec. Sec. Sec. Not more than
less than or 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
equal to 100% in [deg]F (15
diluent Type B [deg]C)
Di-tert-butyl 4 Sec. Sec. Sec. Not more than
peroxide, not 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
more than 32% in [deg]F (15
diluent type A [deg]C)
Isopropyl cumyl 4 Sec. Sec. Sec. Not more than
hydro-peroxide, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
not more than [deg]F (15
72% in diluent [deg]C)
type A
p-Menthyl hydro- 4 Sec. Sec. Sec. Not more than
peroxide, not 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
more than 72% in [deg]F (15
diluent type A [deg]C)
Pinanyl hydro- 4 Sec. Sec. Sec. Not more than
peroxide, not 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
more than 50% in [deg]F (15
diluent type A [deg]C)
-----------
3110 Organic peroxide, 4 Sec. Sec. Sec. Not more than
Type F, solid 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
[deg]F (15
[deg]C)
[[Page 335]]
Dicumyl peroxide 4 Sec. Sec. Sec. Not more than
less than r 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
equal to 100% [deg]F (15
with inert [deg]C)
solids
-----------
Maximum quantity
per portable
tank 2,000 kg
3119 Organic peroxide, 4 Sec. Sec. Sec. Not more than As approved by As approved by
Type F, liquid, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59 Assoc. Admin. Assoc. Admin.
temperature [deg]F (15
controlled [deg]C)
tert-Butyl 4 Sec. Sec. Sec. Not more than +30 [deg]C +35 [deg]C
peroxyacetate, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
not more than [deg]F (15
32% in diluent [deg]C)
Type B
tert-Butyl peroxy- 4 Sec. Sec. Sec. Not more than +15 [deg]C +20 [deg]C
2- 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
ethylhexanoate, [deg]F (15
not more than [deg]C)
32% in diluent
type B
tert-Butyl 4 Sec. Sec. Sec. Not more than +5 [deg]C +10 [deg]C
peroxypivalate, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
not more than [deg]F (15
27% in diluent [deg]C)
Type B
tert-Butyl peroxy- 4 Sec. Sec. Sec. Not more than +35 [deg]C +40 [deg]C
3,5,5-trimethyl- 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
hexanoate, not [deg]F (15
more than 32% in [deg]C)
dileunt type B
Di-(3,5,5- 4 Sec. Sec. Sec. Not more than 0 [deg]C +5 [deg]C
trimethyl- 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
hexanoyl) [deg]F (15
peroxide, not [deg]C)
more htan 38% in
diluent type A
Peroxyacetic 4 Sec. Sec. Sec. Not more than +30 [deg]C +35 [deg]C
acid, distilled, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
stabilized, not [deg]F (15
more than 41% [deg]C)
-----------
3120 Organic peroxide 4 Sec. Sec. Sec. Not more than As approved by As approved by
Type F, solid, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59 Assoc. Admin Assoc. Admin
temperature [deg]F (15
controlled [deg]C)
-----------
3229 Self-reactive 4 Sec. Sec. Sec. Not more than
liquid Type F 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
[deg]F (15
[deg]C)
-----------
3230 Self-reactive 4 Sec. Sec. Sec. Not more than
solid Type F 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59
[deg]F (15
[deg]C)
-----------
[[Page 336]]
3239 Self-reactive 4 Sec. Sec. Sec. Not more than As approved by As approved by
liquid Type F, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59 Assoc. Admin. Assoc. Admin.
temperature [deg]F (15
controlled [deg]C)
-----------
3240 Self-reactive 4 Sec. Sec. Sec. Not more than As approved by As approved by
solid Type F, 178.274(d)(2) 178.275(d)(3) 178.275(g)(1) 90% at 59 Assoc. Admin. Assoc. Admin.
temperature [deg]F (15
controlled [deg]C)
--------------------------------------------------------------------------------------------------------------------------------------------------------
[[Page 337]]
(iv) The following portable tank instruction applies to portable
tanks used for the transportation of liquefied compressed gases. The T50
table provides the UN identification number and proper shipping name for
each liquefied compressed gas authorized to be transported in a T50
portable tank. The table provides maximum allowable working pressures,
bottom opening requirements, pressure relief device requirements and
degree of filling requirements for each liquefied compressed gases
permitted for transportation in a T50 portable tank. In the minimum test
pressure column, ``small'' means a portable tank with a diameter of 1.5
meters or less when measured at the widest part of the shell,
``sunshield'' means a portable tank with a shield covering at least the
upper third of the shell, ``bare'' means no sunshield or insulation is
provided, and ``insulated'' means a complete cladding of sufficient
thickness of insulating material necessary to provide a minimum
conductance of not more than 0.67 w/m2/k. In the pressure
relief requirements column, the word ``Normal'' denotes that a frangible
disc as specified in Sec. 178.276(e)(3) of this subchapter is not
required. The T50 table follows:
Portable Tank Code T50
[Portable tank code T50 applies to liquefied compressed gases.]
----------------------------------------------------------------------------------------------------------------
Max. allowable
Non-refrigerated working pressure Pressure relief
UN No. liquefied (bar) small; bare; Openings below requirements (see Maximum filling
compressed gases sunshield; liquid level Sec. 178.27(e)) density (kg/l)
insulated
----------------------------------------------------------------------------------------------------------------
1005......... Ammonia, 29.0.............. Allowed........... Sec. 0.53
anhydrous. 25.7.............. 178.276(e)(3).
22.0..............
19.7..............
--------------
1009......... Bromotrifluoromet 38.0.............. Allowed........... Normal............ 1.13
hane or 34.0..............
Refrigerant gas 30.0..............
R 13B1. 27.5..............
--------------
1010......... Butadienes, 7.5............... Allowed........... Normal............ 0.55
stabilized. 7.0...............
7.0...............
7.0...............
--------------
1011......... Butane........... 7.0............... Allowed........... Normal............ 0.51
7.0...............
7.0...............
7.0...............
--------------
1012......... Butylene......... 8.0............... Allowed........... Normal............ 0.53
7.0...............
7.0...............
7.0...............
--------------
1017......... Chlorine......... 19.0.............. Not Allowed....... Sec. 1.25
17.0.............. 178.276(e)(3).
15.0..............
13.5..............
--------------
1018......... Chlorodifluoromet 26.0.............. Allowed........... Normal............ 1.03
hane or 24.0..............
Refrigerant gas 21.0..............
R 22. 19.0..............
--------------
1020......... Chloropentafluoro 23.0.............. Allowed........... Normal............ 1.06
ethane or 20.0..............
Refrigerant gas 18.0..............
R 115. 16.0..............
--------------
1021......... 1-Chloro-1,2,2,2- 10.3.............. Allowed........... Normal............ 1.2
tetrafluoroethan 9.8...............
e or Refrigerant 7.9...............
gas R 124. 7.0...............
--------------
[[Page 338]]
1027......... Cyclopropane..... 18.0.............. Allowed........... Normal............ 0.53
16.0..............
14.5..............
13.0..............
--------------
1028......... Dichlorodifluorom 16.0.............. Allowed........... Normal............ 1.15
ethane or 15.0..............
Refrigerant gas 13.0..............
R 12. 11.5..............
--------------
1029......... Dichlorofluoromet 7.0............... Allowed........... Normal............ 1.23
hane or 7.0...............
Refrigerant gas 7.0...............
R 21. 7.0...............
--------------
1030......... 1,1- 16.0.............. Allowed........... Normal............ 0.79
Difluoroethane 14.0..............
or Refrigerant 12.4..............
gas R 152a. 11.0..............
--------------
1032......... Dimethylamine, 7.0............... Allowed........... Normal............ 0.59
anhydrous. 7.0...............
7.0...............
7.0...............
--------------
1033......... Dimethyl ether... 15.5.............. Allowed........... Normal............ 0.58
13.8..............
12.0..............
10.6..............
--------------
1036......... Ethylamine....... 7.0............... Allowed........... Normal............ 0.61
7.0...............
7.0...............
7.0...............
--------------
1037......... Ethyl chloride... 7.0............... Allowed........... Normal............ 0.8
7.0...............
7.0...............
7.0...............
--------------
1040......... Ethylene oxide Only authorized in Not allowed....... Sec. 0.78
with nitrogen up 10 bar 178.276(e)(3).
to a total insulatedportable
pressure of 1MPa tanks.
(10 bar) at 50
[deg]C.
--------------
1041......... Ethylene oxide See MAWP Allowed........... Normal............ See Sec.
and carbon defination in 173.32(f)
dioxide mixture Sec. 178.276(a).
with more than
9% butnot more
than 87%
ethylene oxide.
--------------
1055......... Isobutylene...... 8.1............... Allowed........... Normal............ 0.52
7.0...............
7.0...............
7.0...............
--------------
1060......... Methyl acetylene 28.0.............. Allowed........... Normal............ 0.43
and propadiene 24.5..............
mixture, 22.0..............
stabilized. 20.0..............
--------------
1061......... Methylamine, 10.8.............. Allowed........... Normal............ 0.58
anhydrous. 9.6...............
7.8...............
7.0...............
--------------
[[Page 339]]
1062......... Methyl bromide... 7.0............... Not allowed....... Sec. 1.51
7.0............... 178.276(e)(3).
7.0...............
7.0...............
--------------
1063......... Methyl chloride 14.5.............. Allowed........... Normal............ 0.81
or Refrigerant 12.7..............
gas R 40. 11.3..............
10.0..............
--------------
1064......... Methyl mercaptan. 7.0............... Not allowed....... Sec. 0.78
7.0............... 178.276(e)(3).
7.0...............
7.0...............
--------------
1067......... Dinitrogen 7.0............... Not allowed....... Sec. 1.3
tetroxide. 7.0............... 178.276(e)(3).
7.0...............
7.0...............
--------------
1075......... Petroleum gas, See MAWP Allowed........... Normal............ See Sec.
liquefied. definition in 173.32(f)
Sec. 178.276(a).
--------------
1077......... Propylene........ 28.0.............. Allowed........... Normal............ 0.43
24.5..............
22.0..............
20.0..............
--------------
1078......... Refrigerant gas, See MAWP Allowed........... Normal............ See Sec.
n.o.s.. definition in 173.32(f)
Sec. 178.276(a).
--------------
1079......... Sulphur dioxide.. 11.6.............. Not allowed....... Sec. 1.23
10.3.............. 178.276(e)(3).
8.5...............
7.6...............
--------------
1082......... Trifluorochloroet 17.0.............. Not allowed....... Sec. 1.13
hylene, 15.0.............. 178.276(e)(3).
stabilized or 13.1..............
Refrigerant gas 11.6..............
R 1113.
--------------
1083......... Trimethylamine, 7.0............... Allowed........... Normal............ 0.56
anhydrous. 7.0...............
7.0...............
7.0...............
--------------
1085......... Vinyl bromide, 7.0............... Allowed........... Normal............ 1.37
stabilized. 7.0...............
7.0...............
7.0...............
--------------
1086......... Vinyl chloride, 10.6.............. Allowed........... Normal............ 0.81
stabilized. 9.3...............
8.0...............
7.0...............
--------------
1087......... Vinyl methyl 7.0............... Allowed........... Normal............ 0.67
ether, 7.0...............
stabilized. 7.0...............
7.0...............
--------------
1581......... Chloropicrin and 7.0............... Not Allowed....... Sec. 1.51
methyl bromide 7.0............... 178.276(e)(3).
mixture. 7.0...............
7.0...............
--------------
[[Page 340]]
1582......... Chloropicrin and 19.2.............. Not allowed....... Sec. 0.81
methyl chloride 16.9.............. 178.276(e)(3).
mixture. 15.1..............
13.1..............
--------------
1858......... Hexafluoropropyle 19.2.............. Allowed........... Normal............ 1.11
ne compressed or 16.9..............
Refrigerant gas 15.1..............
R 1216. 13.1..............
--------------
1912......... Methyl chloride 15.2, 13.0, 11.6, Allowed........... Normal............ 0.81
and methylene 10.1.
chloride mixture.
NA 1954...... Insecticide See MAWP Allowed........... Normal............ Sec. 173.32(f)
gases, definition in
flammable, Sec. 178.276(a).
n.o.s..
--------------
1958......... 1,2-Dichloro- 7.0............... Allowed........... Normal............ 1.3
1,1,2,2- 7.0...............
tetrafluoroethan 7.0...............
e or Refrigerant 7.0...............
gas R 114.
--------------
1965......... Hydrocarbon gas, See MAWP Allowed........... Normal............ See Sec.
mixture definition in 173.32(f)
liquefied, 178.276(a).
n.o.s..
--------------
1969......... Isobutane........ 8.5............... Allowed........... Normal............ 0.49
7.5...............
7.0...............
7.0...............
--------------
1973......... Chlorodifluoromet 28.3.............. Allowed........... Normal............ 1.05
hane and 25.3..............
chloropentafluor 22.8..............
oethane mixture 20.3..............
with fixed
boiling point,
withapproximatel
y 49%
chlorodifluorome
thane or
Refrigerant gas
R502.
--------------
1974......... Chlorodifluorobro 7.4............... Allowed........... Normal............ 1.61
momethane or 7.0...............
Refrigerant gas 7.0...............
R 12B1. 7.0...............
--------------
1976......... Octafluorocyclobu 8.8............... Allowed........... Normal............ 1.34
tane or 7.8...............
Refrigerant gas 7.0...............
RC 318. 7.0...............
--------------
1978......... Propane.......... 22.5.............. Allowed........... Normal............ 0.42
20.4..............
18.0..............
16.5..............
--------------
1983......... 1-Chloro-2,2,2- 7.0............... Allowed........... Normal............ 1.18
trifluoroethane 7.0...............
or Refrigerant 7.0...............
gas R 133a. 7.0...............
--------------
2035......... 1,1,1- 31.0.............. Allowed........... Normal............ 0.76
Trifluoroethane 27.5..............
compressed or 24.2..............
Refrigerant gas 21.8..............
R 143a.
--------------
2424......... Octafluoropropane 23.1.............. Allowed........... Normal............ 1.07
or Refrigerant 20.8..............
gas R 218. 18.6..............
16.6..............
--------------
[[Page 341]]
2517......... 1-Chloro-1,1- 8.9............... Allowed........... Normal............ 0.99
difluoroethane 7.8...............
or Refrigerant 7.0...............
gas R 142b. 7.0...............
--------------
2602......... Dichlorodifluorom 20.0.............. Allowed........... Normal............ 1.01
ethane and 18.0..............
difluoroethane 16.0..............
azeotropic 14.5..............
mixture with
approximately
74%
dichlorodifluoro
methane or
Refrigerant gas
R 500.
--------------
3057......... Trifluoroacetyl 14.6.............. Not allowed....... Sec. 1.17
chloride. 12.9.............. 178.276(e)(3).
11.3..............
9.9...............
--------------
3070......... Ethylene oxide 14.0.............. Allowed........... Sec. 1.09
and 12.0.............. 178.276(e)(3).
dichlorodifluoro 11.0..............
methane mixture 9.0...............
with not more
than 12.5%
ethylene oxide.
--------------
3153......... Perfluoro (methyl 14.3.............. Allowed........... Normal............ 1.14
vinyl ether). 13.4..............
11.2..............
10.2..............
--------------
3159......... 1,1,1,2- 17.7.............. Allowed........... Normal............ 1.04
Tetrafluoroethan 15.7..............
e or Refrigerant 13.8..............
gas R 134a. 12.1..............
--------------
3161......... Liquefied gas, See MAWP Allowed........... Normal............ Sec. 173.32(f)
flammable, definition in
n.o.s.. Sec. 178.276(a).
--------------
3163......... Liquefied gas, See MAWP Allowed........... Normal............ Sec. 173.32(f)
n.o.s.. definition in
Sec. 178.276(a).
--------------
3220......... Pentafluoroethane 34.4.............. Allowed........... Normal............ 0.95
or Refrigerant 30.8..............
gas R 125. 27.5..............
24.5..............
--------------
3252......... Difluoromethane 43.0.............. Allowed........... Normal............ 0.78
or Refrigerant 39.0..............
gas R 32. 34.4..............
30.5..............
--------------
3296......... Heptafluoropropan 16.0.............. Allowed........... Normal............ 1.2
e or Refrigerant 14.0..............
gas R 227. 12.5..............
11.0..............
--------------
3297......... Ethylene oxide 8.1............... Allowed........... Normal............ 1.16
and 7.0...............
chlorotetrafluor 7.0...............
oethane mixture, 7.0...............
with not more
than 8.8%
ethylene oxide.
--------------
3298......... Ethylene oxide 25.9.............. Allowed........... Normal............ 1.02
and 23.4..............
pentafluoroethan 20.9..............
e mixture, with 18.6..............
not more than
7.9% ethylene
oxide.
--------------
[[Page 342]]
3299......... Ethylene oxide 16.7.............. Allowed........... Normal............ 1.03
and 14.7..............
tetrafluoroethan 12.9..............
e mixture, with 11.2..............
not more than
5.6% ethylene
oxide.
--------------
3318......... Ammonia solution, See MAWP Allowed........... Sec. Sec. 173.32(f)
relative density definition in 178.276(e)(3).
less than 0.880 178.276(a).
at 15 [deg]C in
water, with more
than 50% ammonia.
--------------
3337......... Refrigerant gas R 31.6.............. Allowed........... Normal............ 0.84
404A. 28.3..............
25.3..............
22.5..............
--------------
3338......... Refrigerant gas R 31.3.............. Allowed........... Normal............ 0.95
407A. 28.1..............
25.1..............
22.4..............
--------------
3339......... Refrigerant gas R 33.0.............. Allowed........... Normal............ 0.95
407B. 29.6..............
26.5..............
23.6..............
--------------
3340......... Refrigerant gas R 29.9.............. Allowed........... Normal............ 0.95
407C. 26.8..............
23.9..............
21.3..............
----------------------------------------------------------------------------------------------------------------
(v) When portable tank instruction T75 is referenced in Column (7)
of the Sec. 172.101 Table, the applicable refrigerated liquefied gases
are authorized to be transported in portable tanks in accordance with
the requirements of Sec. 178.277 of this subchapter.
(vi) UN and IM portable tank codes/special provisions. When a
specific portable tank instruction is specified by a T Code in Column
(7) of the Sec. 172.101 Table for a specific hazardous material, a
Specification portable tank conforming to an alternative tank
instruction may be used if:
(A) the alternative portable tank has a higher or equivalent test
pressure (for example, 4 bar when 2.65 bar is specified);
(B) the alternative portable tank has greater or equivalent wall
thickness (for example, 10 mm when 6 mm is specified);
(C) the alternative portable tank has a pressure relief device as
specified in the T Code. If a frangible disc is required in series with
the reclosing pressure relief device for the specified portable tank,
the alternative portable tank must be fitted with a frangible disc in
series with the reclosing pressure relief device; and
(D) With regard to bottom openings--
(1) When two effective means are specified, the alternative portable
tank is fitted with bottom openings having two or three effective means
of closure or no bottom openings; or
(2) When three effective means are specified, the portable tank has
no bottom openings or three effective means of closure; or
(3) When no bottom openings are authorized, the alternative portable
tank must not have bottom openings.
(vii) When a hazardous material is not assigned a portable tank T
Code or TP 9 is referenced in Column (7) of the Sec. 172.101 Table, the
hazardous material may only be transported in a portable tank if
approved by the Associate Administrator.
(viii) Portable tank special provisions are assigned to certain
hazardous
[[Page 343]]
materials to specify requirements that are in addition to those provided
by the portable tank instructions or the requirements in part 178 of
this subchapter. Portable tank special provisions are designated with
the abbreviation TP (tank provision) and are assigned to specific
hazardous materials in Column (7) of the Sec. 172.101 Table. The
following is a list of the portable tank special provisions:
Code/Special Provisions
TP1 The maximum degree of filling must not exceed the degree of
filling determined by the following:
[GRAPHIC] [TIFF OMITTED] TN21JN01.000
Where:
tr is the maximum mean bulk temperature during transport, and
tf is the temperature in degrees celsius of the liquid during
filling.
TP2 a. The maximum degree of filling must not exceed the degree of
filling determined by the following:
[GRAPHIC] [TIFF OMITTED] TN21JN01.001
Where:
tr is the maximum mean bulk temperature during transport,
tf is the temperature in degrees celsius of the liquid during
filling, and
[alpha] is the mean coefficient of cubical expansion of the liquid
between the mean temperature of the liquid during filling
(tf) and the maximum mean bulk temperature during
transportation (tr) both in degrees celsius.
b. For liquids transported under ambient conditions [alpha] may be
calculated using the formula:
[GRAPHIC] [TIFF OMITTED] TN21JN01.009
Where:
d15 and d50 are the densities (in units of mass
per unit volume) of the liquid at 15 [deg]C (59 [deg]F) and 50 [deg]C
(122 [deg]F), respectively.
TP3 For materials transported under elevated temperatures, the
maximum degree of filling is determined by the following:
[GRAPHIC] [TIFF OMITTED] TR31JY03.000
Where:
dt is the density of the material at the maximum mean bulk
temperature during transport; and
df is the density of the material at the temperature in
degrees celsius of the material during filling; and
TP4 The maximum degree of filling for portable tanks must not exceed
90%.
TP5 For a portable tank used for the transport of flammable
refrigerated liquefied gases or refrigerated liquefied oxygen, the
maximum rate at which the portable tank may be filled must not exceed
the liquid flow capacity of the primary pressure relief system rated at
a pressure not exceeding 120 percent of the portable tank's design
pressure. For portable tanks used for the transport of refrigerated
liquefied helium and refrigerated liquefied atmospheric gas (except
oxygen), the maximum rate at which the tank is filled must not exceed
the liquid flow capacity of the pressure relief device rated at 130
percent of the portable tank's design pressure. Except for a portable
tank containing refrigerated liquefied helium, a portable tank shall
have an outage of at least two percent below the inlet of the pressure
relief device or pressure control valve, under conditions of incipient
opening, with the portable tank in a level attitude. No outage is
required for helium.
TP6 To prevent the tank from bursting in an event, including fire
engulfment (the conditions prescribed in CGA pamphlet S-1.2 (IBR, see
Sec. 171.7 of this subchapter) may be used to consider the fire
engulfment condition), it must be equipped with pressure relief devices
that are adequate in relation to the capacity of the tank and the nature
of the hazardous material transported.
TP7 The vapor space must be purged of air by nitrogen or other
means.
TP8 A portable tank having a minimum test pressure of 1.5 bar (150
kPa) may be used when the flash point of the hazardous material
transported is greater than 0 [deg]C (32 [deg]F).
TP9 A hazardous material assigned to special provision TP9 in Column
(7) of the Sec. 172.101 Table may only be transported in a portable
tank if approved by the Associate Administrator.
TP10 The portable tank must be fitted with a lead lining at least 5
mm (0.2 inches) thick. The lead lining must be tested annually to ensure
that it is intact and functional. Another suitable lining material may
be used if approved by the Associate Administrator.
TP12 This material is considered highly corrosive to steel.
[[Page 344]]
TP13 Self-contained breathing apparatus must be provided when this
hazardous material is transported by sea.
TP16 The portable tank must be protected against over and under
pressurization which may be experienced during transportation. The means
of protection must be approved by the approval agency designated to
approve the portable tank in accordance with the procedures in part 107,
subpart E, of this subchapter. The pressure relief device must be
preceded by a frangible disk in accordance with the requirements in
Sec. 178.275(g)(3) of this subchapter to prevent crystallization of the
product in the pressure relief device.
TP17 Only inorganic non-combustible materials may be used for
thermal insulation of the tank.
TP18 The temperature of this material must be maintained between 18
[deg]C (64.4 [deg]F) and 40 [deg]C (104 [deg]F) while in transportation.
Portable tanks containing solidified methacrylic acid must not be
reheated during transportation.
TP19 The calculated wall thickness must be increased by 3 mm at the
time of construction. Wall thickness must be verified ultrasonically at
intervals midway between periodic hydraulic tests (every 2.5 years). The
portable tank must not be used if the wall thickness is less than that
prescribed by the applicable T code in Column (7) of the Table for this
material.
TP20 This hazardous material must only be transported in insulated
tanks under a nitrogen blanket.
TP21 The wall thickness must not be less than 8 mm. Portable tanks
must be hydraulically tested and internally inspected at intervals not
exceeding 2.5 years.
TP22 Lubricants for portable tank fittings (for example, gaskets,
shut-off valves, flanges) must be oxygen compatible.
TP24 The portable tank may be fitted with a device to prevent the
build up of excess pressure due to the slow decomposition of the
hazardous material being transported. The device must be in the vapor
space when the tank is filled under maximum filling conditions. This
device must also prevent an unacceptable amount of leakage of liquid in
the case of overturning.
TP25 Sulphur trioxide 99.95% pure and above may be transported in
tanks without an inhibitor provided that it is maintained at a
temperature equal to or above 32.5 [deg]C (90.5 [deg]F).
TP26 The heating device must be exterior to the shell. For UN 3176,
this requirement only applies when the hazardous material reacts
dangerously with water.
TP27 A portable tank having a minimum test pressure of 4 bar (400
kPa) may be used provided the calculated test pressure is 4 bar or less
based on the MAWP of the hazardous material, as defined in Sec. 178.275
of this subchapter, where the test pressure is 1.5 times the MAWP.
TP28 A portable tank having a minimum test pressure of 2.65 bar (265
kPa) may be used provided the calculated test pressure is 2.65 bar or
less based on the MAWP of the hazardous material, as defined in Sec.
178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
TP29 A portable tank having a minimum test pressure of 1.5 bar
(150.0 kPa) may be used provided the calculated test pressure is 1.5 bar
or less based on the MAWP of the hazardous materials, as defined in
Sec. 178.275 of this subchapter, where the test pressure is 1.5 times
the MAWP.
TP30 This hazardous material may only be transported in insulated
tanks.
TP31 This hazardous material may only be transported in tanks in the
solid state.
TP37 IM portable tanks are only authorized for the shipment of
hydrogen peroxide solutions in water containing 72% or less hydrogen
peroxide by weight. Pressure relief devices shall be designed to prevent
the entry of foreign matter, the leakage of liquid and the development
of any dangerous excess pressure. In addition, the portable tank must be
designed so that internal surfaces may be effectively cleaned and
passivated. Each tank must be equipped with pressure relief devices
conforming to the following requirements:
------------------------------------------------------------------------
Total
Concentration of hydrogen per peroxide solution \1\
------------------------------------------------------------------------
52% or less................................................... 11
Over 52%, but not greater than 60%............................ 22
Over 60%, but not greater than 72%............................ 32
------------------------------------------------------------------------
\1\ Total venting capacity in standard cubic feet hour (S.C.F.H.) per
pound of hydrogen peroxide solution.
TP38 Each portable tank must be insulated with an insulating
material so that the overall thermal conductance at 15.5 [deg]C (60
[deg]F) is no more than 1.5333 kilojoules per hour per square meter per
degree Celsius (0.075 Btu per hour per square foot per degree
Fahrenheit) temperature differential. Insulating materials may not
promote corrosion to steel when wet.
TP44 Each portable tank must be made of stainless steel, except that
steel other than stainless steel may be used in accordance with the
provisions of Sec. 173.24b(b) of this subchapter. Thickness of
stainless steel for tank shell and heads must be the greater of 7.62 mm
(0.300 inch) or the thickness required for a portable tank with a design
pressure at least equal to 1.5 times the vapor pressure of the hazardous
material at 46 [deg]C (115 [deg]F).
TP45 Each portable tank must be made of stainless steel, except that
steel other than stainless steel may be used in accordance
[[Page 345]]
with the provisions of 173.24b(b) of this subchapter. Thickness of
stainless steel for portable tank shells and heads must be the greater
of 6.35 mm (0.250 inch) or the thickness required for a portable tank
with a design pressure at least equal to 1.3 times the vapor pressure of
the hazardous material at 46 [deg]C (115 [deg]F).
TP46 Portable tanks in sodium metal service are not required to be
hydrostatically retested.
(8) ``W'' codes. These provisions apply only to transportation by
water:
Code/Special Provisions
W7 Vessel stowage category for uranyl nitrate hexahydrate solution is
``D'' as defined in Sec. 172.101(k)(4).
W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric
uranium metal is ``D'' as defined in Sec. 172.101(k)(4).
W9 When offered for transportation by water, the following Specification
packagings are not authorized unless approved by the Associate
Administrator: woven plastic bags, plastic film bags, textile bags,
paper bags, IBCs and bulk packagings.
W41 When offered for transportation by water, this material must be
packaged in bales and be securely and tightly bound with rope, wire or
similar means.
[Amdt. 172-123, 55 FR 52582, Dec. 21, 1990]
Editorial Note: For Federal Register citations affecting Sec.
172.102, see the List of CFR Sections Affected which appears in the
Finding Aids section of the printed volume and on GPO Access.
Subpart C_Shipping Papers